SHOJI Sunao

researchmap

Profile and Settings

• Name (Japanese)

  SUNAO

• Name (Kana)

  SHOJI

Degree

• Doctor of Science, Ritsumeikan University, Sep. 2014

Research Interests

• Organic Chemistry
• Supramolecular Chemistry
• Photochemistry
• Photosynthesis

Research Areas

• Life sciences, Bioorganic chemistry
• Nanotechnology/Materials, Structural/physical organic chemistry
• Nanotechnology/Materials, Organic functional materials
• Nanotechnology/Materials, Inorganic and coordination chemistry

Research Experience

• Apr. 2023, 9999, Nara Women's University, Faculty of Engineering, Assistant Professor, Japan
• Apr. 2021, Mar. 2023, Hokkaido University, Division of Applied Chemistry, Faculty of Engineering, Specially Appointed Assistant Professor
• Jan. 2021, Mar. 2023, Hokkaido University, The Institute for Chemical Reaction Design and Discovery (WPI-ICReDD), Specially Appointed Assistant Professor
• Apr. 2019, Dec. 2020, Hokkaido University, Division of Applied Chemistry, Faculty of Engineering, Postdoctoral Fellow
• Apr. 2016, Mar. 2019, Ritsumeikan University, Research Organization of Science and Technology, Postdoctoral Fellow
• Jan. 2018, Mar. 2018, Universität Würzburg, Prof. Frank Würthner研究室, 客員研究員
• Oct. 2014, Mar. 2016, JSPS Research Fellowship for Young Scientist (PD)
• Apr. 2014, Sep. 2014, JSPS Research Fellowship for Young Scientist (DC2)

Education

• Apr. 2012, Sep. 2014, Ritsumeikan University, Graduate School of Life Sciences, Advanced Life Sciences
• Apr. 2010, Mar. 2012, Ritsumeikan University, Graduate School of Science and Engineering, Advanced Science and Engineering Major
• Apr. 2006, Mar. 2010, Ritsumeikan University, College of Science and Engineering, Department of Applied Chemistry

Teaching Experience

• English for chemistry, Hokkaido University, Apr. 2021, Aug. 2022
• Molecular Function Analysis, Nara Women's University, Apr. 2023, 9999
• Molecular Function Analysis Seminar, Nara Women's University, Oct. 2023, 9999
• Supramolecular System Design Seminar, Nara Women's University, Oct. 2023, 9999
• Supramolecular System Design, Nara Women's University, Apr. 2023, 9999
• Exercises in Organic Chemistry, Nara Women's University, Apr. 2024, 9999
• Laboratory Work in Organic & Inorganic Chemistry, Nara Women's University, Oct. 2023, 9999
• PICASO, Nara Women's University, Apr. 2024, Aug. 2024
• Passage, Nara Women's University, Apr. 2024, 9999
• Pre-degree Seminar, Nara Women's University, Apr. 2024, 9999
• 技術者倫理, Nara Women's University, Dec. 2024, Jan. 2025
• 生活工学概論A, Nara Women's University, Oct. 2023, Jan. 2024

Association Memberships

• 錯体化学会
• 高分子学会
• THE JAPANESE PHOTOCHEMISTRY ASSOCIATION
• The Chemical Society of Japan
• The society of Physical Organic Chemistry, Japan
• ホスト−ゲスト・超分子化学研究会
• 複合系の光機能研究会

Media Coverage

• 植物の成長を促すビニール開発, 楽しいわが家, Jan. 2023
• 赤色発光する希土類錯体で植物成長促進の実証に成功, Chem-Station 第455回スポットライトリサーチ, 30 Dec. 2022, Internet
• フィルムに塗布して植物成長促進, 科学新聞, 18 Nov. 2022, Paper
• 植物の成長促すビニール, 読売新聞, 06 Nov. 2022, Paper
• 野菜の重量4割増、植物の成長促す透明フィルムがスゴい, 28 Oct. 2022, Yahoo!ニュース
• 植物成長促すフィルム 紫外線→赤色光変換, 日刊工業新聞, 27 Oct. 2022, Paper
• 「赤色光」で野菜３割大きく, 日本経済新聞(北海道版), 19 Mar. 2022, Paper
• 第235回スポットライトリサーチ「葉緑素だけが集積したナノシート」, Chem-Station, 09 Dec. 2019, Internet
• 『人工光合成』実現へ葉緑素を利用, 朝日新聞デジタル, 31 Oct. 2019, Internet
• 葉緑素 微小シート 光合成の仕組みなど解明へ, 日刊工業新聞, 27 Oct. 2019, Paper

Ⅱ．研究活動実績

Published Papers

• Refereed, International Journal of Hydrogen Energy, Elsevier BV, Quantitative evaluation of hydrogen absorption by detecting non-absorbed hydrogen in electrochemical hydrogen permeation test, Yuya Mizushiri; Sunao Shoji; Yuichi Kitagawa; Yasuchika Hasegawa; Koji Fushimi, Jan. 2024, Scientific journal, 10.1016/j.ijhydene.2023.10.236

  DOI URL
• Refereed, Inorganic Chemistry, American Chemical Society (ACS), Sandglass-Typed Single Chameleon Luminophore for Water Mapping Measurements: Intramolecular Energy Migrations in the Hydrophilic Tb(III)/Sm(III) Cluster, Yasuchika Hasegawa; Yuki Konishi; Masaki Enokido; Sunao Shoji; Mengfei Wang; Koji Fushimi; Yuichi Kitagawa, 21 Sep. 2023, 62, 41, 16794, 16800, Scientific journal, 10.1021/acs.inorgchem.3c02219

  PermalinkDOI URL
• Refereed, Electrochimica Acta, Elsevier BV, Investigation of the dissolution/passivation mechanisms on Fe-Cr alloys in acidic Na2SO4 solution using online ICP-OES, Akihiro Fujimura; Sunao Shoji; Yuichi Kitagawa; Yasuchika Hasegawa; Takashi Doi; Koji Fushimi, Sep. 2023, 463, 142843, 142843, Scientific journal, 10.1016/j.electacta.2023.142843

  DOI URL
• Refereed, Communications Chemistry, Springer Science and Business Media LLC, Thermally-assisted photosensitized emission in a trivalent terbium complex, Yuichi Kitagawa; Kaori Shima; Takuma Nakai; Marina Kumagai; Shun Omagari; Pedro Paulo Ferreira da Rosa; Sunao Shoji; Koji Fushimi; Yasuchika Hasegawa, Abstract Luminescent lanthanide complexes containing effective photosensitizers are promising materials for use in displays and sensors. The photosensitizer design strategy has been studied for developing the lanthanide-based luminophores. Herein, we demonstrate a photosensitizer design using dinuclear luminescent lanthanide complex, which exhibits thermally-assisted photosensitized emission. The lanthanide complex comprised Tb(III) ions, six tetramethylheptanedionates, and phosphine oxide bridge containing a phenanthrene frameworks. The phenanthrene ligand and Tb(III) ions are the energy donor (photosensitizer) and acceptor (emission center) parts, respectively. The energy-donating level of the ligand (lowest excited triplet (T₁) level = 19,850 cm⁻¹) is lower than the emitting level of the Tb(III) ion (⁵D₄ level = 20,500 cm⁻¹). The long-lived T₁ state of the energy-donating ligands promoted an efficient thermally-assisted photosensitized emission of the Tb(III) acceptor (⁵D₄ level), resulting in a pure-green colored emission with a high photosensitized emission quantum yield (73%)., 22 Jun. 2023, 6, 1, 122, Scientific journal, 10.1038/s42004-023-00922-5

  PermalinkURLDOI URL
• Refereed, Frontiers in Chemistry, Frontiers Media SA, Characteristic stacked structures and luminescent properties of dinuclear lanthanide complexes with pyrene units, Takuma Nakai; Kaori Shima; Sunao Shoji; Koji Fushimi; Yasuchika Hasegawa; Yuichi Kitagawa, A novel design strategy of stacked organic fluorophores using dinuclear lanthanide (Ln(III)) complexes is demonstrated for the formation of excimer. The dinuclear Ln(III) complexes are composed of two Ln(III) (Eu(III) or Gd(III)) ions, six hexafluoroacetylacetonate (hfa), and two pyrene-based phosphine oxide ligands. Single-crystal analysis revealed a rigid pyrene-stacked structure via CH-F (pyrene/hfa) intramolecular interactions. The rigid aggregation structures of the two-typed organic ligands around Ln(III) resulted in high thermal stability (decomposition temperature: 340°C). The aggregated ligands exhibited excimer-type green emission from the stacked pyrene-center. The change in the Ln(III) ion promotes effective shifts of excimer emissions (Gd(III):500 nm, Eu(III):490 nm). The organic aggregation system using red-luminescent Eu(III) also provides temperature-sensitive ratiometric emission composed of π-π* and 4f-4f transitions by energy migration between aggregated ligands and Eu(III)., 14 Apr. 2023, 11, 041508, Scientific journal, 10.3389/fchem.2023.1154012

  PermalinkDOI URL
• Refereed, Journal of The Electrochemical Society, The Electrochemical Society, Initiation of Sulfide Stress Cracking Using Potentiostatic Liquid-Phase Ion Gun, K. Fushimi; H. Yanagimoto; S. Nakatsuji; S. Shoji; Y. Kitagawa; Y. Hasegawa; K. Baba, A liquid-phase ion gun (LPIG) was used to create a local H₂S enriched environment near Cr-containing steel surface in Na₂S solutions in attempt to induce sulfide stress cracking on the specimen surface. In a 1.5 mM Na₂S solution, anodic polarization of LPIG Pt microelectrode at a potential of 1.90 V vs SHE resulted in that local solution was successfully acidified to below pH 4, a pseudo-sour environment. When Cr-containing steels were potentiostatically polarized under this pseudo-sour environment by LPIG, sulfides were formed on the specimen surface depending on Cr-concentration, specimen potential, and chloride ion in solution. When LPIG was operated on Cr-containing steels subjected to tensile stress using a four-point bending tester, cracks were formed on the steel surface., 01 Apr. 2023, 170, 4, 041508, 041508, Scientific journal, 10.1149/1945-7111/accd26

  PermalinkURLDOI URL
• Refereed, Angewandte Chemie International Edition, Wiley, Synthesis of Bicyclo[1.1.1]pentane (BCP)‐Based Straight‐Shaped Diphosphine Ligands, Hideaki Takano; Hitomi Katsuyama; Hiroki Hayashi; Miyu Harukawa; Makoto Tsurui; Sunao Shoji; Yasuchika Hasegawa; Satoshi Maeda; Tsuyoshi Mita, 24 Mar. 2023, 62, e202303435, Scientific journal, 10.1002/anie.202303435

  PermalinkDOI URL
• Refereed, ChemPlusChem, Wiley, Luminescent Lanthanide Complexes for Effective Oxygen‐Sensing and Singlet Oxygen Generation, Yuichi Kitagawa; Takuma Nakai; Shota Hosoya; Sunao Shoji; Yasuchika Hasegawa, 09 Feb. 2023, 2023, e202200445, Scientific journal, 10.1002/cplu.202200445

  PermalinkURLDOI URL
• Refereed, Dalton Transactions, Royal Society of Chemistry (RSC), Evaluation of oxygen-containing pentadentate ligands with pyridine/quinoline/isoquinoline binding sites via structural and electrochemical properties of mononuclear copper(II) complexes, Yuji Mikata; Mizuho Uchida; Hinata Koike; Sunao Shoji; Yutaka Ohsedo; Yasushi Kawai; Takashi Matsuo, Eighteen mononuclear copper(II) complexes with oxygen-containing N4O1 pentadentate ligands were prepared. The ligand library consists of 2-aminoethanol derivatives ((Ar1CH2)(Ar2CH2)NCH2CH2OCH2Ar3) bearing three nitrogen-containing heteroaromatics (Ars) including pyridine, quinoline and isoquinoline via..., 2023, Scientific journal, 10.1039/d3dt02814c

  PermalinkDOI URL
• Refereed, Dalton Transactions, Royal Society of Chemistry (RSC), Enhanced circularly polarized luminescence of chiral Eu(iii) coordination polymers with structural strain, Makoto Tsurui; Yuichi Kitagawa; Sunao Shoji; Koji Fushimi; Yasuchika Hasegawa, Three types of Eu(iii) coordination polymers with distorted chiral ligands were prepared for elucidating the relationship between their structural distortions, ligand-to-metal charge transfer, and circularly polarized luminescence properties., 2023, 52, 3, 796, 805, Scientific journal, 10.1039/d2dt03422k

  PermalinkDOI URL
• Refereed, Electrochimica Acta, Elsevier BV, Development of a quasi-on-time ICP-OES for analyzing electrode reaction products, Akihiro Fujimura; Sunao Shoji; Yuichi Kitagawa; Yasuchika Hasegawa; Takashi Doi; Koji Fushimi, Nov. 2022, 433, 141246, 141246, Scientific journal, 10.1016/j.electacta.2022.141246

  DOI URL
• Refereed, Scientific Reports, Springer Science and Business Media LLC, Plant growth acceleration using a transparent Eu3+-painted UV-to-red conversion film, S. Shoji; H. Saito; Y. Jitsuyama; K. Tomita; Q. Haoyang; Y. Sakurai; Y. Okazaki; K. Aikawa; Y. Konishi; K. Sasaki; K. Fushimi; Y. Kitagawa; T. Suzuki; Y. Hasegawa, Abstract The stimulation of photosynthesis is a strategy for achieving sustainable plant production. Red light is useful for plant growth because it is absorbed by chlorophyll pigments, which initiate natural photosynthetic processes. Ultraviolet (UV)-to-red wavelength-converting materials are promising candidates for eco-friendly plant cultures that do not require electric power. In this study, transparent films equipped with a UV-to-red wavelength-converting luminophore, the Eu³⁺ complex, were prepared on commercially available plastic films for plant growth experiments. The present Eu³⁺-based films absorb UV light and exhibit strong red luminescence under sunlight. Eu³⁺-painted films provide significant growth acceleration with size increment and biomass production for vegetal crops and trees in a northern region. The plants cultured with Eu³⁺-painted films had a 1.2-fold height and 1.4-fold total body biomass than those cultures without the Eu³⁺ luminophores. The present film can promote the plant production in fields of agriculture and forestry., 26 Oct. 2022, 12, 1, 12155, Scientific journal, 10.1038/s41598-022-21427-6

  PermalinkURLDOI URL
• Refereed, Coordination Chemistry Reviews, Elsevier BV, Amorphous lanthanide complexes for organic luminescent materials, Joe Hayashi; Sunao Shoji; Yuichi Kitagawa; Yasuchika Hasegawa, Sep. 2022, 467, 214607, 214607, Scientific journal, 10.1016/j.ccr.2022.214607

  DOI URL
• Refereed, Bulletin of the Chemical Society of Japan, The Chemical Society of Japan, Self-Assembly of a Zinc Bacteriochlorophyll-d Analog with a Lipophilic Tertiary Amide Group in the 17-Substituent, Sunao Shoji; Vladimir Stepanenko; Frank Würthner; Hitoshi Tamiaki, 15 Jul. 2022, 95, 7, 1083, 1085, Scientific journal, 10.1246/bcsj.20220128

  PermalinkDOI URL
• Refereed, ChemPlusChem, Wiley, Effective Photosensitization in Excited‐State Equilibrium: Brilliant Luminescence of Tb ^III Coordination Polymers Through Ancillary Ligand Modifications, Yuichi Kitagawa; Ryoma Moriake; Tomoko Akama; Koki Saito; Kota Aikawa; Sunao Shoji; Koji Fushimi; Masato Kobayashi; Tetsuya Taketsugu; Yasuchika Hasegawa, 13 Jul. 2022, e202200151, Scientific journal, 10.1002/cplu.202200151

  PermalinkURLDOI URL
• Refereed, Nature Communications, Springer Science and Business Media LLC, Preparation of photonic molecular trains via soft-crystal polymerization of lanthanide complexes, Pedro Paulo Ferreira da Rosa; Yuichi Kitagawa; Sunao Shoji; Hironaga Oyama; Keisuke Imaeda; Naofumi Nakayama; Koji Fushimi; Hidehiro Uekusa; Kosei Ueno; Hitoshi Goto; Yasuchika Hasegawa, Abstract Soft-crystals are defined as flexible molecular solids with highly ordered structures and have attracted attention in molecular sensing materials based on external triggers and environments. Here, we show the soft-crystal copolymerization of green-luminescent Tb(III) and yellow-luminescent Dy(III) coordination centers. Soft-crystal polymerization is achieved via transformation of monomeric dinuclear complexes and polymeric structures with respect to coordination number and geometry. The structural transformation is characterized using single-crystal and powder X-ray diffraction. The connected Tb(III) crystal-Dy(III) crystal show photon energy transfer from the Dy(III) centre to the Tb(III) centre under blue light excitation (selective Dy(III) centre excitation: 460 ± 10 nm). The activation energy of the energy transfer is estimated using the temperature-dependent emission lifetimes and emission quantum yields, and time-dependent density functional theory (B3LYP) calculations. Luminescence-conductive polymers, photonic molecular trains, are successfully prepared via soft-crystal polymerization on crystal media with remarkable long-range energy migration., Jul. 2022, 13, 1, 3660, Scientific journal, 10.1038/s41467-022-31164-z

  PermalinkURLDOI URL
• Refereed, The Journal of Physical Chemistry B, American Chemical Society (ACS), Asymmetric Lumino-Transformer: Circularly Polarized Luminescence of Chiral Eu(III) Coordination Polymer with Phase-Transition Behavior, Makoto Tsurui; Yuichi Kitagawa; Sunao Shoji; Hitomi Ohmagari; Miki Hasegawa; Masayuki Gon; Kazuo Tanaka; Masato Kobayashi; Tetsuya Taketsugu; Koji Fushimi; Yasuchika Hasegawa, 26 May 2022, 126, 20, 3799, 3807, Scientific journal, 10.1021/acs.jpcb.2c01639

  PermalinkDOI URL
• Refereed, Eurasian Journal of Forests Research, Application of a new film for horticultural use to convert UV-light to photosynthetic active radiation, Satoshi Kitaoka; Tauro Shinano; Takashi Suzuki; Sunao Shoji; Yasuchika Hasegawa, Apr. 2022, 22, 73, 77, Research institution, 10.14943/EJFR.22.73

  DOI URL
• Refereed, Chemistry – A European Journal, Wiley, Tribo‐Excited Chemical Reaction Using an Eu ^III Complex with a Stacked Anthracene Framework, Yuichi Kitagawa; Ayu Naito; Kota Aikawa; Kaori Shima; Sunao Shoji; Koji Fushimi; Yasuchika Hasegawa, A spin-selective tribo-chemical reaction using a dinuclear lanthanide complex is demonstrated for the first time. The dinuclear complex is composed of two Eu-III ions, hexafluoroacetylacetonato ligands, and anthracene-based phosphine oxide bridges. Single-crystal analysis revealed a face-to-face-type anthracene dimer structure in the dinuclear Eu-III complex. Mechanical stimulus on the dinuclear Eu-III complex induced selective formation of oxidized anthracene. The tribo-chemical reaction is based on a characteristic energy-transfer pathway for the selective formation of an excited triplet state., 16 Mar. 2022, 28, 16, e202104401, Scientific journal, 10.1002/chem.202104401

  PermalinkURLDOI URL
• Refereed, Chemistry Letters, The Chemical Society of Japan, Luminescent Eu(III)-based Coordination Polymers for Photonic Materials, Yasuchika Hasegawa; Sunao Shoji; Yuichi Kitagawa, 05 Feb. 2022, 51, 2, 185, 196, Scientific journal, 10.1246/cl.210650

  PermalinkDOI URL
• Refereed, Materials Letters, Elsevier BV, Amide-bridged Eu(III) coordination polymer for stable luminescent glass material, Joe Hayashi; Sunao Shoji; Yuichi Kitagawa; Koji Fushimi; Yasuchika Hasegawa, A novel lanthanide coordination polymer composed of Eu(III) ion, low-vibrational frequency hfa (hfa: hexafluoroacetylacetonato), and phosphine oxide ligand with amide groups (dpba: N,N'-(ethane-1,2-diyl)bis(4-(diphenylphosphoryl)benzamide)), Eu-dpba is reported. A lanthanide coordination polymer with alkyl groups (dph: 1,6-bis(diphenylphosphoryl)hexane), Eu-dph is also prepared, as a reference sample. Eu-dpba showed phase transition behavior at 128 °C, although alkyl-bridged Eu-dph showed no phase transition behavior by differential scanning calorimeter measurements. The smooth surface on the Eu-dpba after heat treatment was observed using scanning electron microscope. The photophysical properties were estimated using the emission spectra and the emission lifetimes. We found that the emission quantum yield of Eu-dpba with heat treatment is the same as that of Eu-dpba without heat treatment., Aug. 2021, 297, 130012, 130012, Scientific journal, 10.1016/j.matlet.2021.130012

  DOI URLScopus URLScopus Citedby URL
• Refereed, Tetsu-to-Hagane, Iron and Steel Institute of Japan, In-situ Observation of Corrosion Initiation Occurring on NaCl Nanoparticles-deposited Carbon Steel Surfaces, Koji Fushimi; Haruka Okuyama; Kai Ohshimizu; Sunao Shoji; Yuichi Kitagawa; Yasuchika Hasegawa, 2021, 107, 12, 1011, 1019, Scientific journal, 10.2355/tetsutohagane.tetsu-2021-049

  PermalinkDOI URL
• Refereed, Chemistry Letters, The Chemical Society of Japan, Zinc 7,8-Dihydroxylated Chlorophyll-a Derivative as a Synthetic Model of Natural Bacteriochlorophyll-a, Daichi Funakoshi; Yosaku Nomura; Sunao Shoji; Hitoshi Tamiaki, 10 Sep. 2020, 49, 11, 1403, 1405, Scientific journal, 10.1246/cl.200585

  PermalinkDOI URL
• Refereed, ChemPlusChem, Wiley, An Europium (III) Luminophore with Pressure‐Sensing Units: Effective Back Energy Transfer in Coordination Polymers with Hexadentate Porous Stable Networks, Yasuchika Hasegawa; Takuya Sawanobori; Yuichi Kitagawa; Sunao Shoji; Koji Fushimi; Yuta Nakasaka; Takao Masuda; Ichiro Hisaki, A luminescent EuIII coordination polymer with O2 -sensing units under air, EuIII -hcpt (hcpt: 2,3,6,7,10,11-hexakis(4-carboxy-phenyl)triphenylene), is reported. The hexadentate carboxylic acids in hcpt ligands play an important role in the formation of tight-packed three-dimensional networks in EuIII -hcpt, giving hyper thermo-stable structures (decomposition temperature=420 °C). The three-dimensional porous network promotes bright luminescence (4f-4f emission quantum yield=70 %). The emission lifetime of EuIII -hcpt under vacuum (0.86 ms) was twice as large as that under O2 (0.48 ms, 1 atom:101.3 kPa). The Arrhenius analysis of the emission decay profile indicates that the back energy transfer (BEnT) from the emitting level of the europium(III) ion to the excited T1 state of the hcpt ligand should be activated at room temperature. The gradual decrease of emission lifetime is caused by the BEnT process in EuIII -hcpt. Finally, an advanced pressure-sensitive luminophore is demonstrated., Sep. 2020, 85, 9, 1989, 1993, Scientific journal, True, 10.1002/cplu.202000513

  PermalinkURLDOI URL
• Refereed, Tetrahedron, Elsevier BV, Covalent heterodyads of synthetic chlorophyll derivatives linked with linear rigid substituents at the 20-positions constructing photoexcited energy transfer systems, Sunao Shoji; Yosaku Nomura; Hitoshi Tamiaki, Apr. 2020, 76, 17, 131130, 131130, Scientific journal, 10.1016/j.tet.2020.131130

  DOI URL
• Refereed, Dyes and Pigments, Elsevier BV, Synthetic substituted boronates of dihydroxy-bacteriochlorin absorbing and emitting far-red to near-infrared light as bacteriopheophytin-a analogs, Daichi Funakoshi; Yosaku Nomura; Sunao Shoji; Hitoshi Tamiaki, Apr. 2020, 175, 108155, 108155, Scientific journal, 10.1016/j.dyepig.2019.108155

  DOI URL
• Refereed, Scientific Reports, Springer Science and Business Media LLC, Bioinspired supramolecular nanosheets of zinc chlorophyll assemblies, Sunao Shoji; Tetsuya Ogawa; Shogo Matsubara; Hitoshi Tamiaki, Two-dimensional sheet-like supramolecules have attracted much attention from the viewpoints of their potential application as functional (nano)materials due to unique physical and chemical properties. One of the supramolecular sheet-like nanostructures in nature is visible in the self-assemblies of bacteriochlorophyll-c–f pigments inside chlorosomes, which are major components in the antenna systems of photosynthetic green bacteria. Herein, we report artificial chlorosomal supramolecular nanosheets prepared by the self-assembly of a synthetic zinc 3¹-methoxy-chlorophyll derivative having amide and urea groups in the substituent at the 17-position. The semi-synthetic zinc chlorophyll derivative kinetically formed dimeric species and transformed into more thermodynamically stable chlorosomal J-aggregates in the solid state. The kinetically and thermodynamically formed self-assemblies had particle-like and sheet-like supramolecular nanostructures, respectively. The resulting nanosheets of biomimetic chlorosomal J-aggregates had flat surfaces and well-ordered supramolecular structures. The artificial sheet-like nanomaterial mimicking chlorosomal bacteriochlorophyll-c–f J-aggregates was first constructed by the model molecule, and is potentially useful for various applications including artificial light-harvesting antennas and photosyntheses., Dec. 2019, 9, 1, 14006, 14006, Scientific journal, 10.1038/s41598-019-50026-1

  PermalinkURLDOI URL
• Refereed, Photochemical & Photobiological Sciences, Royal Society of Chemistry (RSC), Heterodimers of zinc and free-base chlorophyll derivatives co-assembled in biomimetic chlorosomal J-aggregates, Sunao Shoji; Yosaku Nomura; Hitoshi Tamiaki,

  Free-base chlorophyll derivatives covalently linked with their zinc complex accepted singlet excitation energy from chlorosomal self-aggregates in their co-assembly.

  , 2019, 18, 2, 555, 562, Scientific journal, 10.1039/c8pp00468d

  PermalinkDOI URL
• Refereed, Dyes and Pigments, Elsevier BV, Supramolecular light-harvesting antenna system by co-aggregates of zinc (bacterio)chlorophyll-a derivatives with biomimetic chlorosomal self-assemblies, Sunao Shoji; Hitoshi Tamiaki, Jan. 2019, 160, 514, 518, Scientific journal, 10.1016/j.dyepig.2018.08.026

  DOI URL
• Refereed, ChemPhysChem, Wiley, Self-Assemblies of Zinc Bacteriochlorophyll-d Analogues Having Amide, Ester, and Urea Groups as Substituents at 17-Position and Observation of Lamellar Supramolecular Nanostructures, Sunao Shoji; Tetsuya Ogawa; Takeshi Hashishin; Hitoshi Tamiaki, Chlorosomes are unique light-harvesting apparatuses in photosynthetic green bacteria. Single chlorosomes contain a large number of bacteriochlorophyll (BChl)-c, -d, -e, and -f molecules, which self-assemble without protein assistance. These BChl self-assemblies involving specific intermolecular interactions (MgO3(2)-HO=C13(1) and - stacks of chlorin skeletons) in a chlorosome have been reported to be round-shaped rods (or tubes) with diameters of 5 or 10nm, or lamellae with a layer spacing of approximately 2nm. Herein, the self-assembly of synthetic zinc BChl-d analogues having ester, amide, and urea groups in the 17-substituent is reported. Spectroscopic analyses indicate that the zinc BChl-d analogues self-assemble in a nonpolar organic solvent in a similar manner to natural chlorosomal BChls with additional assistance by hydrogen-bonding of secondary amide (or urea) groups (CON-HO=CNH). Microscopic analyses of the supramolecules of a zinc BChl-d analogue bearing amide and urea groups show round- or square-shaped rods with widths of about 65nm. Cryogenic TEM shows a lamellar arrangement of the zinc chlorin with a layer spacing of 1.5nm inside the rod. Similar thick rods are also visible in the micrographs of self-assemblies of zinc BChl-d analogues with one or two secondary amide moieties in the 17-substituent., 17 Apr. 2018, 19, 8, 913, 920, Scientific journal, 10.1002/cphc.201701044

  PermalinkDOI URL
• Refereed, Journal of Photochemistry and Photobiology A: Chemistry, Elsevier BV, Self-aggregation of synthetic chlorophyll-c derivative and effect of C17-acrylate residue on bridging green gap in chlorosomal model, Shogo Matsubara; Sunao Shoji; Hitoshi Tamiaki, May 2017, 340, 53, 61, Scientific journal, 10.1016/j.jphotochem.2017.02.021

  DOI URL
• Refereed, Journal of Photochemistry and Photobiology A: Chemistry, Elsevier BV, In vitro self-assemblies of bacteriochlorophylls-c from Chlorobaculum tepidum and their supramolecular nanostructures, Sunao Shoji; Tadashi Mizoguchi; Hitoshi Tamiaki, Dec. 2016, 331, 190, 196, Scientific journal, 10.1016/j.jphotochem.2015.11.003

  DOI URL
• Refereed, Nano Letters, American Chemical Society (ACS), Nanotubes of Biomimetic Supramolecules Constructed by Synthetic Metal Chlorophyll Derivatives, Sunao Shoji; Tetsuya Ogawa; Takeshi Hashishin; Shin Ogasawara; Hiroaki Watanabe; Hisanao Usami; Hitoshi Tamiaki, Various supramolecular nanotubes have recently been built up by lipids, peptides, and other organic molecules. Major light-harvesting (LH) antenna systems in a filamentous anoxygenic phototroph, Chloroflexus (Cfl.) aurantiacus, are called chlorosomes and contain photofunctional single-wall supramolecular nanotubes with approximately 5 nm in their diameter. Chlorosomal supramolecular nanotubes of Cfl. aurantiacus are constructed by a large amount of bacteriochlorophyll(BChl)-c molecules. Such a pigment self-assembles in a chlorosome without any assistance from the peptides, which is in sharp contrast to the other natural photosynthetic LH antennas. To mimic chlorosomal supramolecular nanotubes, synthetic models were prepared by the modification of naturally occurring chlorophyll(Chl)-a molecule. Metal complexes (magnesium, zinc, and cadmium) of the Chl derivative were synthesized as models of natural chlorosomal BChls. These metal Chl derivatives self-assembled in hydrophobic environments, and their supramolecules were analyzed by spectroscopic and microscopic techniques. Cryo-transmission electron microscopic images showed that the zinc and cadmium Chl derivatives could form single-wall supramolecular nanotubes and their outer and inner diameters were approximately 5 and 3 nm, respectively. Atomic force microscopic images suggested that the magnesium Chl derivative formed similar nanotubes to those of the corresponding zinc and cadmium complexes. Three chlorosomal single-wall supramolecular nanotubes of the metal Chl derivatives were prepared in the solid state and would be useful as photofunctional materials., 08 Jun. 2016, 16, 6, 3650, 3654, Scientific journal, 10.1021/acs.nanolett.6b00781

  PermalinkDOI URL
• Refereed, Photochemistry and Photobiology, Wiley, Synthesis of Zinc Chlorophyll Homo/Hetero-Dyads and their Folded Conformers with Porphyrin, Chlorin, and Bacteriochlorinπ-Systems, Hitoshi Tamiaki; Kazuhiro Fukai; Hideki Shimazu; Sunao Shoji, Jan. 2014, 90, 1, 121, 128, Scientific journal, 10.1111/php.12173

  DOI URL
• Refereed, Bioorganic & Medicinal Chemistry, Elsevier BV, Pheophytinization kinetics of chlorophyll c under weakly acidic conditions: Effects of acrylic acid residue at the 17-position, Kana Sadaoka; Sunao Shoji; Keiya Hirota; Yusuke Tsukatani; Taichi Yoshitomi; Hitoshi Tamiaki; Shigenori Kashimura; Yoshitaka Saga, Nov. 2013, 21, 22, 6915, 6919, Scientific journal, 10.1016/j.bmc.2013.09.032

  DOI URL
• Refereed, Chemical Physics Letters, Elsevier BV, Reconstruction of rod self-aggregates of natural bacteriochlorophylls-c from Chloroflexus aurantiacus, Sunao Shoji; Tadashi Mizoguchi; Hitoshi Tamiaki, Jul. 2013, 578, 102, 105, Scientific journal, 10.1016/j.cplett.2013.06.012

  DOI URL
• Refereed, Chemistry Letters, The Chemical Society of Japan, Microflow-driven Temporal Self-assembly of Amphiphilic Molecules, Munenori Numata; Momoko Takayama; Sunao Shoji; Hitoshi Tamiaki, 05 Dec. 2012, 41, 12, 1689, 1691, Scientific journal, 10.1246/cl.2012.1689

  PermalinkDOI URL
• Refereed, Proceedings of the National Academy of Sciences, Proceedings of the National Academy of Sciences, Ubiquity and quantitative significance of detoxification catabolism of chlorophyll associated with protistan herbivory, Y. Kashiyama; A. Yokoyama; Y. Kinoshita; S. Shoji; H. Miyashiya; T. Shiratori; H. Suga; K. Ishikawa; A. Ishikawa; I. Inouye; K.-i. Ishida; D. Fujinuma; K. Aoki; M. Kobayashi; S. Nomoto; T. Mizoguchi; H. Tamiaki, Chlorophylls are essential components of the photosynthetic apparati that sustain all of the life forms that ultimately depend on solar energy. However, a drawback of the extraordinary photosensitizing efficiency of certain chlorophyll species is their ability to generate harmful singlet oxygen. Recent studies have clarified the catabolic processes involved in the detoxification of chlorophylls in land plants, but little is understood about these strategies in aquatic ecosystem. Here, we report that a variety of heterotrophic protists accumulate the chlorophyll a catabolite 13(2),17(3)-cyclopheophorbide a enol (cPPB-aE) after their ingestion of algae. This chlorophyll derivative is nonfluorescent in solution, and its inability to generate singlet oxygen in vitro qualifies it as a detoxified catabolite of chlorophyll a. Using a modified analytical method, we show that cPPB-aE is ubiquitous in aquatic environments, and it is often the major chlorophyll a derivative. Our findings suggest that cPPB-aE metabolism is one of the most important, widely distributed processes in aquatic ecosystems. Therefore, the herbivorous protists that convert chlorophyll a to cPPB-aE are suggested to play more significant roles in the modern oceanic carbon flux than was previously recognized, critically linking microscopic primary producers to the macroscopic food web and carbon sequestration in the ocean., 23 Oct. 2012, 109, 43, 17328, 17335, Scientific journal, 10.1073/pnas.1207347109

  PermalinkDOI URL
• Refereed, Chemistry - A European Journal, Wiley, Construction of Chlorosomal Rod Self-Aggregates in the Solid State on Any Substrates from Synthetic Chlorophyll Derivatives Possessing an Oligomethylene Chain at the 17-Propionate Residue, Sunao Shoji; Takeshi Hashishin; Hitoshi Tamiaki, Chlorosomes are one of the most unique natural light-harvesting antennas and their supramolecular nanostructures are still under debate. Chlorosomes contain bacteriochlorophyll (BChl)-c, d and e molecules and these pigments self-aggregate under a hydrophobic environment inside a chlorosome. The self-aggregates are mainly constructed by the following three interactions: hydrogen bonding, coordination bonding and pp stacking. Supramolecular nanostructures of self-aggregated BChls have been widely investigated by spectroscopic and microscopic techniques. Model compounds of such chlorosomal BChl molecules have been synthesized and the effects of esterified long alkyl chains at the 17-propionate residue for their self-aggregation have been studied. Structurally simple zinc chlorophyll derivatives possessing an oligomethylene chain as the esterifying group at the 17-propionate residue were prepared as chlorosomal BChl models. The synthetic zinc BChls self-aggregated in nonpolar organic solvents to give precipitates. The resulting insoluble self-aggregated solids were investigated on a variety of substrates, including hydrophobic, neutral and hydrophilic substrates, by visible absorption, circular dichroism and polarized light absorption spectroscopies, as well as atomic force, transmission electron and scanning electron microscopies. The self-aggregates of synthetic Zn-BChls formed rods with an approximately 5 nm diameter and wires with further elongated growth of the rods (aspect ratio >200). The diameter size was consistent with that estimated for natural chlorosomal rods in a filamentous anoxygenic phototroph, Chloroflexus aurantiacus. The supramolecular formation and stability of the rod on the examined substrates depended on the length of an oligomethylene chain at the 17-propionate residue as well as on the surface properties. Especially, the number of the 5 nm rods on the substrates increased with an elongation of the chain., 15 Oct. 2012, 18, 42, 13331, 13341, Scientific journal, 10.1002/chem.201201935

  DOI URL
• Refereed, Bulletin of the Chemical Society of Japan, The Chemical Society of Japan, Self-Assembly of Zinc Bacteriochlorophyll d Derivative Possessing a Triethoxysilyl Group at the 17-Propionate Residue, Naoya Takahashi; Sunao Shoji; Hitoshi Tamiaki; Yoshitaka Saga, 15 Sep. 2012, 85, 9, 989, 994, Scientific journal, 10.1246/bcsj.20120043

  PermalinkDOI URL
• Refereed, Photochemical & Photobiological Sciences, Royal Society of Chemistry (RSC), Photooxidative cleavage of zinc 20-substituted chlorophyll derivatives: conformationally P-helix-favored formation of regioselectively 19–20 opened linear tetrapyrroles, Hitoshi Tamiaki; Yukihiro Okamoto; Yuji Mikata; Sunao Shoji, 2012, 11, 6, 898, 907, Scientific journal, 10.1039/c1pp05301a

  PermalinkDOI URL
• Refereed, Inorganica Chimica Acta, Elsevier BV, Cd2+-selective fluorescence enhancement of N,N’-bis(2-quinolylmethyl)-N,N’-dimethyl-1,2-phenylenediamine derivatives, Yuji Mikata; Kaho Kawakami; Miho Nagaoka; Sunao Shoji; Hideo Konno; Takashi Matsuo, May 2024, 565, 121968, 121968, Scientific journal, 10.1016/j.ica.2024.121968

  DOI URL
• Refereed, Journal of The Electrochemical Society, The Electrochemical Society, Passive Film Formed on Si-Mn Steel in Boric Acid-Borate Buffer at 6.5, Koji Fushimi; Kanta Higa; Akihiro Fujimura; Sunao Shoji; Yuichi Kitagawa; Yasuchika Hasegawa; Hideki Katayama, Passivity-maintaining current of high-strength (Si-Mn) steel in boric acid-borate buffer at pH 6.5 was larger than that of ferrite/pearlite (F/P) steel. Charge transfer resistance of the Si-Mn steel surface passivated at 1.10 V vs SHE in pH 6.5 buffer was smaller than that of F/P steel surface. Nano-analyses using AES and STEM revealed the details of the structure and components of the passive film on the Si-Mn steel. The inferiorities of passivity of Si-Mn steel were suggested to be due to the alloying components and metallurgical structure to increase the strength of the steel., 01 Feb. 2024, 171, 2, 021502, 021502, Scientific journal, 10.1149/1945-7111/ad27b7

  PermalinkURLDOI URL
• Refereed, Scientific Reports, Structure-changeable luminescent Eu(III) complex as a human cancer grade probing system for brain tumor diagnosis., Mengfei Wang; Masaya Kono; Yusaku Yamaguchi; Jahidul Islam; Sunao Shoji; Yuichi Kitagawa; Koji Fushimi; Sora Watanabe; Go Matsuba; Akihisa Yamamoto; Motomu Tanaka; Masumi Tsuda; Shinya Tanaka; Yasuchika Hasegawa, Accurate determination of human tumor malignancy is important for choosing efficient and safe therapies. Bioimaging technologies based on luminescent molecules are widely used to localize and distinguish active tumor cells. Here, we report a human cancer grade probing system (GPS) using a water-soluble and structure-changeable Eu(III) complex for the continuous detection of early human brain tumors of different malignancy grades. Time-dependent emission spectra of the Eu(III) complexes in various types of tumor cells were recorded. The radiative rate constants (kr), which depend on the geometry of the Eu(III) complex, were calculated from the emission spectra. The tendency of the kr values to vary depended on the tumor cells at different malignancy grades. Between T = 0 and T = 3 h of invasion, the kr values exhibited an increase of 4% in NHA/TS (benign grade II gliomas), 7% in NHA/TSR (malignant grade III gliomas), and 27% in NHA/TSRA (malignant grade IV gliomas). Tumor cells with high-grade malignancy exhibited a rapid upward trend in kr values. The cancer GPS employs Eu(III) emissions to provide a new diagnostic method for determining human brain tumor malignancy., 22 Jan. 2024, 14, 1, 778, 778, Scientific journal, True, 10.1038/s41598-023-50138-9

  DOI URL
• Refereed, Molecules, MDPI AG, Cd2+-Selective Fluorescence Enhancement of Bisquinoline Derivatives with 2-Aminoethanol Skeleton, Yuji Mikata; Aya Tsuruta; Hinata Koike; Sunao Shoji; Hideo Konno, The development of fluorescent Cd2+ sensors requires strict selectivity over Zn2+ because of the high availability of Zn2+ in the natural environment. In this paper, bisquinoline-based fluorescent sensors with a 2-aminoethanol backbone were investigated. The weak coordination ability of quinoline compared to well-studied pyridine is suitable for Cd2+ selectivity rather than Zn2+. In the presence of 3 equiv. of metal ions, TriMeO-N,O-BQMAE (N,O-bis(5,6,7-trimethoxy-2-quinolylmethyl)-2-methylaminoethanol (3)), as well as its N,N-isomer TriMeO-N,N-BQMAE (N,N-bis(5,6,7-trimethoxy-2-quinolylmethyl)-2-methoxyethylamine (6)), exhibits Cd2+-selective fluorescence enhancement over Zn2+ in DMF-HEPES buffer (1:1, 50 mM HEPES, 0.1 M KCl, pH = 7.5) (IZn/ICd = 26–34%), which has similar selectivity in comparison to the corresponding ethylenediamine derivative TriMeOBQDMEN (N,N’-bis(5,6,7-trimethoxy-2-quinolylmethyl)-N,N’-dimethylethylenediamine) under the same experimental condition (IZn/ICd = 24%). The fluorescence mechanisms of N,O- and N,N-isomers of BQMAE are quite different, judging from the fluorescence lifetimes of their metal complexes. The Cd2+ complex with TriMeO-N,O-BQMAE (3) exhibits a long fluorescence lifetime similar to that of TriMeOBQDMEN via intramolecular excimer emission, whereas the Cd2+ complex with TriMeO-N,N-BQMAE (6) exhibits a short lifetime from monomer emission., 11 Jan. 2024, 29, 2, 369, 369, Scientific journal, 10.3390/molecules29020369

  PermalinkDOI URL
• Refereed, The Journal of Physical Chemistry C, American Chemical Society (ACS), Size-Control Synthesis and Luminescence Properties of Eu(III) Coordination Particles, Masaki Enokido; Kensei Sasaki; Sunao Shoji; Mengfei Wang; Koji Fushimi; Yuichi Kitagawa; Yasuchika Hasegawa, 01 Dec. 2023, 127, 49, 23785, 23791, Scientific journal, 10.1021/acs.jpcc.3c06499

  PermalinkDOI URL
• Refereed, Inorganic Chemistry, American Chemical Society (ACS), Guest-Responsive Near-Infrared-Luminescent Metal–Organic Cage Organized by Porphyrin Dyes and Yb(III) Complexes, Shota Hosoya; Sunao Shoji; Takayuki Nakanishi; Masato Kobayashi; Mengfei Wang; Koji Fushimi; Tetsuya Taketsugu; Yuichi Kitagawa; Yasuchika Hasegawa, 21 May 2024, 63, 10108, 10113, Scientific journal, 10.1021/acs.inorgchem.4c01348

  PermalinkDOI URL
• Refereed, Inorganic Chemistry, American Chemical Society (ACS), Cd²⁺-Specific Fluorescence Response of Methoxy-Substituted N,N-Bis(2-quinolylmethyl)-2-methoxyaniline Derivatives, Yuji Mikata; Nao Tosaka; Saori Yasuda; Yui Sakurai; Sunao Shoji; Hideo Konno; Takashi Matsuo, 23 Apr. 2024, 63, 18, 8026, 8037, Scientific journal, 10.1021/acs.inorgchem.3c04395

  PermalinkDOI URL
• Refereed, Inorganica Chimica Acta, Elsevier BV, Alkyl substituents control the Cd2+-selectivity of fluorescence enhancement in N,N’-bis(2-quinolylmethyl)ethylenediamine derivatives, Yuji Mikata; Saori Yasuda; Taeka Hagiwara; Hideo Konno; Sunao Shoji, Oct. 2024, 571, 122218, 122218, Scientific journal, 10.1016/j.ica.2024.122218

  DOI URL
• π-4f charge-transfer emission in a trivalent europium complex, Yuichi Kitagawa; Toranosuke Tomikawa; Kota Aikawa; Shiori Miyazaki; Tomoko Akama; Masato Kobayashi; Mengfei Wang; Sunao Shoji; Koji Fushimi; Kiyoshi Miyata; Yuichi Hirai; Takayuki Nakanishi; Ken Onda; Tetsuya Taketsugu; Yasuchika Hasegawa, 29 May 2024, 10.21203/rs.3.rs-4252624/v1

  DOI URL
• Tetsu-to-Hagane, Composition Analysis of Corrosion Products on Steel by Machine Learning of Optical Microscopic Images, Yuki Tsuji; Kota Hirasawa; Sunao Shoji; Yuichi Kitagawa; Yasuchika Hasegawa; Koji Fushimi, 2024, Scientific journal, 10.2355/tetsutohagane.TETSU-2024-056

  DOI URL
• Dalton Transactions, Royal Society of Chemistry (RSC), Structural and electrochemical properties of mononuclear copper(II) complexes with pentadentate ethylenediamine-based ligands with pyridine/quinoline/isoquinoline/quinoxaline binding sites†, Yuji Mikata; Miyu Akedo; Erina Hamamoto; Shoko Yoshida; Sunao Shoji; Yutaka Ohsedo; Tim Storr; Yasuhiro Funahashi; Takashi Matsuo, N-monosubstituted ethylenediamine derivatives with three methylene-tethered aromatic groups ((ArCH2)2NCH2CH2N(R)CH2Ar (R-ArArAr), where Ar = 2-pyridyl, 2-quinolyl, 1- and 3-isoquinolyl and 2-quinoxalyl; R = methyl, benzyl and phenyl) were utilized as pentadentate..., 2024, Scientific journal, 10.1039/d4dt02363c

  PermalinkDOI URL
• Chemistry – A European Journal, Wiley, Luminescence changeable CO2‐storage cylinder: Triple‐stranded helical Eu(III)/Tb(III) fluorinated MOFs with amide linkers, Joe Hayashi; Shinichiro Iwamura; Yuta Nakasaka; Mengfei Wang; Sunao Shoji; Yuichi Kitagawa; Koji Fushimi; Shin R. Mukai; Yasuchika Hasegawa, Triple‐stranded helical lanthanide MOFs with CO2 adsorption properties were investigated. Lanthanide MOFs ([Eu0.1Tb0.9(hfa)3(dpa)]n) are composed of lanthanide luminophores (Eu(III) and/or Tb(III) ions), fluorinated antenna ligands (hfa: hexafluoroacetylacetonate), and polyamide‐type linker ligands (dpa: 4‐(diphenylphosphoryl)‐N‐(4‐(diphenylphosphoryl)phenyl)benzamide). The cylindrical structure was characterized by single‐crystal X‐ray analysis, thermogravimetric analysis, and gas adsorption measurements. The inner surfaces of the cylindrical channels were covered with the fluorine atoms of the hfa ligands. The emission intensity ratio (IEu / ITb) in [Eu0.1Tb0.9(hfa)3(dpa)]n is affected by the CO2 gas adsorption behavior. The change in IEu / ITb value was caused by the intermolecular interactions between the CO2 gas molecules and the fluorinated ligands, resulting in an electronic structural change of the lowest triplet excited state in the photosensitized hfa ligands., 09 Sep. 2024, Scientific journal, 10.1002/chem.202403224

  DOI URL
• Refereed, Chemical Communications, Royal Society of Chemistry (RSC), Biomimetic light-harvesting antennas via the self-assembly of chemically programmed chlorophylls, Shogo Matsubara; Sunao Shoji; Hitoshi Tamiaki, This feature article describes strategies for constructing supramolecular aggregates of (semi)synthetic dyes, particularly chlorophyll derivatives to mimic the photosynthetic light-harvesting antennas., 2024, 60, 86, 12513, 12524, Scientific journal, 10.1039/d4cc04363d

  PermalinkDOI URL

MISC

• カーボン・エネルギー社会協議会(CanApple)ニュースレター, 光合成アンテナ研究から農業へ, 庄司 淳, Jul. 2021, 191
• 化学, 生物から学ぶ効率的な光合成システム –分子レベルで設計された人工光捕集アンテナの構築–, 松原翔吾; 庄司 淳; 民秋 均, Apr. 2021, 75, 6, 70, 71
• Not Refereed, ぶんせき, 希土類錯体分子の構造異性体を利用した光線力学診断と療法の両立, 庄司 淳, 2020
• Not Refereed, NanotechJapan Bulletin, 緑色光合成細菌の光捕集アンテナを模倣したクロロフィル自己集積体のナノ構造観察, 庄司 淳; 小川哲也; 民秋 均, 2020, 13, 1, 1, 6
• Not Refereed, MATERIAL STAGE, 技術情報協会, 天然／人工光合成アンテナの構造・機能と開発動向, 庄司 淳; 民秋 均, 2017, 16, 11, 36, 42

  Permalink
• バイオサイエンスとインダストリー(B&I), ユウロピウム錯体塗布農業用フィルムの被覆による植物の成長促進, 鈴木 卓; 斎藤秀之; 庄司 淳; 長谷川靖哉, Sep. 2023, 81, 5, 412, 413
• バイオサイエンスとインダストリー(B&I), 紫外線を赤色光に変換するフィルムによる植物の成長促進効果, 鈴木 卓; 斎藤秀之; 庄司 淳; 長谷川靖哉, Sep. 2023, 81, 5, 390, 391
• ChemPhysChem, Wiley, Cover Feature: Self‐Assemblies of Zinc Bacteriochlorophyll‐d Analogues Having Amide, Ester, and Urea Groups as Substituents at 17‐Position and Observation of Lamellar Supramolecular Nanostructures (ChemPhysChem 8/2018), Sunao Shoji; Tetsuya Ogawa; Takeshi Hashishin; Hitoshi Tamiaki, 16 Apr. 2018, 19, 8, 893, 893, 10.1002/cphc.201800258

  PermalinkDOI URL
• Chemistry – A European Journal, Wiley, Back Cover: Construction of Chlorosomal Rod Self‐Aggregates in the Solid State on Any Substrates from Synthetic Chlorophyll Derivatives Possessing an Oligomethylene Chain at the 17‐Propionate Residue (Chem. Eur. J. 42/2012), Sunao Shoji; Takeshi Hashishin; Hitoshi Tamiaki, 05 Oct. 2012, 18, 42, 13544, 13544, 10.1002/chem.201290186

  PermalinkDOI URL

Books etc

• 「MgN4」,「ZnN4」, 錯体化合物事典, 錯体化学会, 朝倉書店, 民秋 均; 庄司 淳, MgN4, ZnN4, Sep. 2019, 54, 944p, 9784254141054

  CiNii Books URL
• Lanthanide-Based Wavelength Conversion Materials, Springer Singapore, Y. Hasegawa; Y. Kitagawa; S. Shoji, Oct. 2024
• 希土類錯体蛍光体の植物育成への応用、〈続〉次世代蛍光体材料の開発, シーエムシー出版, 庄司 淳; 長谷川靖哉; 北川裕一; 鈴木 卓; 斎藤秀之, 111–118, Aug. 2024

Presentations

• 高野夏美; 藤村諒大; 庄司 淳; 北川裕一; 長谷川靖哉; 中川 凌吾; 尾﨑 良太; 伏見公志, 電気化学会第90大会, オンラインICP-OES分析による塩化物水溶液中のA4045腐食挙動, Mar. 2023
• 板谷康佑; 鶴井 真; 庄司 淳; 伏見公志; 長谷川靖哉; 北川裕一, 日本化学会第103春季年会, フェナントレン骨格を導入したキラルEu(III)錯体の円偏光発光, Mar. 2023
• 稲毛康太; 庄司 淳; 伏見公志; 北川裕一; 長谷川靖哉, 日本化学会第103春季年会, 2つのホスフィンオキシド基を有するポルフィリンによるYb(III)配位化合物の合成と光物性, Mar. 2023
• 山口優作; 庄司 淳; 王 夢菲; 北川裕一; 伏見公志; 長谷川靖哉, 日本化学会第103春季年会, 溶液中で会合体を形成するアミド基含有Eu(III)錯体の合成と光物性, Mar. 2023
• 藤村諒大; 庄司 淳; 北川裕一; 長谷川靖哉; 土井教史; 伏見公志, 日本鉄鋼協会第185回春季講演大会, 溶液分析による鉄鋼材料の電極反応速度論の検討, Mar. 2023
• S. Shoji, Joint Symposium of Research Faculty of Agriculture and WPI-ICReDD in Hokkaido University, Luminescent paint film using a Eu(III) complex for accelerating plant growth, Mar. 2023
• 山崎佑樹; 鶴井 真; 庄司 淳; 北川裕一; 伏見公志; 長谷川靖哉, 第57回(2022年)高分子学会北海道支部研究発表会, キラルEu(III)配位化合物の連結構造と円偏光発光機能, Jan. 2023
• 辻 湧貴; 庄司 淳; 北川裕一; 長谷川靖哉; 伏見公志, 化学系学協会北海道支部2023年冬季研究発表会, 機械学習を利用した鉄酸化物／水酸化物分類アルゴリズムによる大気腐食挙動の解析, Jan. 2023
• 水尻雄也; 庄司 淳; 北川裕一; 長谷川靖哉; 伏見公志, 化学系学協会北海道支部2023年冬季研究発表会, 水素侵入反応その場定量測定による純鉄中の水素濃度分布の検討, Jan. 2023
• 榎戸雅基; 庄司 淳; 北川裕一; 伏見公志; 長谷川靖哉, 化学系学協会北海道支部2023年冬季研究発表会, スクシンイミドエステルを導入した発光性Eu錯体のアミノ酸応答, Jan. 2023
• 細谷祥太; 庄司 淳; 伏見公志; 北川裕一; 長谷川靖哉, 化学系学協会北海道支部2023年冬季研究発表会, ポルフィリン-Yb(III)四核ケージ状錯体をホスト材料とした分子認識と近赤外発光増強, Jan. 2023
• 中井拓真; 庄司 淳; 伏見公志; 長谷川靖哉; 北川裕一, 第18回学際領域における分子イメージングフォーラム, 発光性Yb(Ⅲ)-Lu(Ⅲ)混合分子結晶の高感度感圧特性, Dec. 2022
• 春川美友; 髙野秀明; 美多 剛; 庄司 淳; 伏見公志; 北川裕一; 長谷川靖哉, 第18回学際領域における分子イメージングフォーラム, Eu(III)配位高分子を用いた広い温度域における感温発光機能, Dec. 2022
• 相川航汰; 庄司 淳; 伏見公志; 長谷川靖哉; 北川裕一, 第12回CSJ化学フェスタ2022, 水を利用したEu(III)錯体の構造変形による発光色変化, Oct. 2022
• 中井拓真; 庄司 淳; 伏見公志; 長谷川靖哉; 北川裕一, 第12回CSJ化学フェスタ2022, 希土類混合分子結晶の遅延発光を利用した超高感度酸素センサー, Oct. 2022
• 富川虎乃輔; 庄司 淳; 赤間知子; 小林正人; 伏見公志; 武次徹也; 長谷川靖哉; 北川裕一, 第12回CSJ化学フェスタ2022, 強アクセプター性配位子を導入したCe(III)錯体の4f-π*電荷移動発光, Oct. 2022
• 春川美友; 髙野秀明; 美多 剛; 庄司 淳; 伏見公志; 北川裕一; 長谷川靖哉, 第12回CSJ化学フェスタ2022, ドナーアクセプターを連結したEu(III)配位高分子の発光機能, Oct. 2022
• 細谷祥太; 庄司 淳; 伏見公志; 北川裕一; 長谷川靖哉, 第12回CSJ化学フェスタ2022, ポルフィリン-Yb(III)ケージ状超分子錯体の光増感発光, Oct. 2022
• 水尻雄也; 庄司 淳; 北川裕一; 長谷川靖哉; 伏見公志, 第69回材料と環境討論会, 非侵入水素定量評価による鉄鋼材料中への水素侵入反応その場解析, Oct. 2022
• 辻湧貴; 庄司 淳; 北川裕一; 長谷川靖哉; 伏見公志, 第69回材料と環境討論会, 機械学習を利用した鉄鋼材料表面に形成する腐食生成物の分類, Oct. 2022
• 大清水 海; 庄司 淳; 北川裕一; 長谷川靖哉; 土井教史; 伏見公志, 第69回材料と環境討論会, 鉄系合金表面上における酸化物薄膜のイメージングエリプソメトリー, Oct. 2022
• 藤村諒大; 庄司 淳; 北川裕一; 長谷川靖哉; 土井教史; 伏見公志, 第69回材料と環境討論会, 溶液分析によるFe系合金の不働態化挙動に関する検討」, Oct. 2022
• 林 穣; 庄司 淳; 北川 裕一; 伏見 公志; 長谷川 靖哉, 第71回高分子討論会, アミド基を有する発光性Eu(III)配位高分子のガラス形成, Sep. 2022
• 鶴井 真; 北川裕一; 庄司 淳; 大曲 仁美; 長谷川美貴; 権 正行; 田中一生; 小林正人; 武次徹也; 伏見公志; 長谷川靖哉, 第71回高分子討論会, キラルEu(III)配位高分子の相転移による構造変化と円偏光発光特性の制御, Sep. 2022
• 小西由姫; 庄司 淳; 北川裕一; 伏見公志; 長谷川靖哉, 第71回高分子討論会, 両親媒性を有する九核希土類(III)クラスターの会合体形成と光機能, Sep. 2022
• 春川美友; 髙野秀明; 美多 剛; 庄司 淳; 伏見公志; 北川裕一; 長谷川靖哉, 第71回高分子討論会, ドナーアクセプター型リンカーを有するEu(III)配位高分子の合成と光物性, Sep. 2022
• 中井拓真; 庄司 淳; 伏見公志; 長谷川靖哉; 北川裕一, 第71回高分子討論会, 多環芳香族骨格を含む希土類分子結晶の酸素センシング機能, Sep. 2022
• 富川虎乃輔; 庄司 淳; 赤間知子; 小林正人; 伏見公志; 武次徹也; 長谷川靖哉; 北川裕一, 第71回高分子討論会, アクセプター性配位子を有するセリウム(III) 錯体の青色発光特性, Sep. 2022
• 細谷祥太; 庄司 淳; 伏見公志; 北川裕一; 長谷川靖哉, 第71回高分子討論会, ポルフィリンを光増感剤としたYb(III)配位化合物の近赤外発光, Sep. 2022
• 相川航汰; 庄司 淳; 伏見公志; 長谷川 靖哉; 北川裕一, 第71回高分子討論会, 強いドナー性配位子を導入したEu(III)錯体のπ軌道から4ｆ軌道の電荷移動発光, Sep. 2022
• 佐々木建晟; 庄司 淳; 北川裕一; 中村一希; 小林範久; 伏見公志; 長谷川靖哉, 第71回高分子討論会, DNA固定化能を有する希土類配位ナノ粒子の発光機能, Sep. 2022
• A. Fujimura; S. Shoji; Y. Kitagawa; Y. Hasegawa; T. Doi; K. Fushimi, EUROCORR 2022, Development of an electrochemical online ICP-OES method for dissolution behavior at non-steady state, Aug. 2022
• 富川⻁乃輔; 庄司 淳; 赤間知子; 小林正人; 伏見公志; 武次徹也; 長谷川靖哉; 北川裕一, 第33回配位化合物の光化学討論会, 4f-π*電荷移動発光を示すセリウム(III)錯体の設計・合成と光物性評価, Aug. 2022
• 中井拓真; 庄司 淳; 伏見公志; 長谷川靖哉; 北川裕一, 第33回配位化合物の光化学討論会, 希土類錯体間のエネルギー移動を利用した高感度酸素センサーの設計とその実証, Aug. 2022
• 細谷祥太; 庄司 淳; 伏見公志; 北川裕一; 長谷川靖哉, 第33回配位化合物の光化学討論会, ポルフィリンを光増感剤としたカゴ状 Yb(III)四核錯体の近赤外発光特性, Aug. 2022
• 春川美友; 髙野秀明; 美多 剛; 庄司 淳; 伏見公志; 北川裕一; 長谷川靖哉, 第33回配位化合物の光化学討論会, Eu(III)配位高分子の架橋部への置換基導入と発光機能, Aug. 2022
• 鶴井 真; 北川裕一; 庄司 淳; 伏見公志; 長谷川靖哉, 第33回配位化合物の光化学討論会, キラル Eu(III)配位高分子の配位幾何学構造と円偏光発光特性, Aug. 2022
• 相川航汰; 庄司 淳; 伏見公志; 谷川靖哉; 北川裕一, 第33回配位化合物の光化学討論会, 強いドナー性配位子を導入した Eu(III)錯体の設計とπ-4f 電荷移動発光特性, Aug. 2022
• 佐々木建晟; 庄司 淳; 北川裕一; 中村一希; 小林範久; 伏見公志; 谷川靖哉, 第33回配位化合物の光化学討論会, 発光性希土類配位ナノ粒子の DNA による機能化, Aug. 2022
• S. Shoji; S. Hosoya; Y. Kitagawa; K. Fushimi; Y. Hasegawa, The 5th International Union of Materials Research Societies International Conference of Young Researchers on Advanced Materials (IUMRS-ICYRAM 2022), Near infrared luminescent supramolecular assemblies based on metal complexes of porphyrin derivatives, Aug. 2022
• 辻湧貴; 庄司 淳; 北川裕一; 長谷川靖哉; 伏見公志, 電気化学会北海道支部５０周年記念若手研究者発表会, 炭素鋼表面における腐食挙動解析に向けた機械学習の適用, Jun. 2022
• 大清水 海; 庄司 淳; 北川裕一; 長谷川靖哉; 伏見公志, 電気化学会北海道支部５０周年記念若手研究者発表会, 偏光カメラを用いたNaCl微粒子に起因する水薄膜形成の高感度観察, Jun. 2022
• 水尻雄也; 庄司 淳; 北川裕一; 長谷川靖哉; 伏見公志, 電気化学会北海道支部５０周年記念若手研究者発表会, フロー型二重電極法を用いたFeへのトラップ水素量その場定量評価, Jun. 2022
• 庄司 淳; 細谷祥太; 北川裕一; 伏見公志; 長谷川靖哉, 第19回ホスト-ゲスト・超分子化学シンポジウム(SHGSC2022), ホスフィンオキシド基を有するポルフィリンを配位子としたケージ状希土類超分子の合成と発光特性, Jun. 2022
• 藤村諒大; 庄司 淳; 北川裕一; 長谷川靖哉; 土井教史; 伏見公志, 材料と環境2022, Online ICP-OES測定を用いた硫酸酸性溶液中におけるFe基二元系合金の不働態化挙動解析, May 2022
• 大清水 海; 庄司 淳; 北川裕一; 長谷川靖哉; 伏見公志, 材料と環境2022, 偏光カメラを用いた酸化物薄膜の高感度観察, May 2022
• 辻 湧貴; 庄司 淳; 北川裕一; 長谷川靖哉; 伏見公志, 材料と環境2022, 機械学習を用いた炭素鋼表面における腐食初期過程の解析, May 2022
• 水尻雄也; 庄司 淳; 北川裕一; 長谷川靖哉; 土井教史; 伏見公志, 材料と環境2022, フロー型二重電極法を用いた非侵入水素と透過水素の同時検出, May 2022
• 佐々木建晟; 庄司 淳; 北川裕一; 中村一希; 小林範久; 伏見公志; 長谷川靖哉, 第38回希土類討論会, 希土類配位ナノ粒子のDNAとの結合に伴う円偏光発光機能, May 2022
• 相川航汰; 庄司 淳; 伏見公志; 長谷川靖哉; 北川裕一, 第38回希土類討論会, π軌道から4f軌道の遷移に基づくカルバゾールEu(III)錯体の電荷移動発光, May 2022
• 小西由姫; 庄司 淳; 北川裕一; 伏見公志; 長谷川靖哉, 第38回希土類討論会, Tb(III)とSm(III)を含む混合九核クラスターの環境に依存した発光特性, May 2022
• 鶴井 真; 北川裕一; 庄司 淳; 大曲仁美; 長谷川美貴; 権 正行; 田中一生; 小林正人; 武次徹也; 伏見公志; 長谷川靖哉, 第38回希土類討論会, キラルEu(III)配位高分子の相転移挙動と発光特性, May 2022
• T. Tomikawa; S. Shoji; T. Akama; M. Kobayashi; K. Fushimi; T. Taketsugu; Y. Hasegawa; Y. Kitagawa, 日本化学会第102春季年会, Synthesis and photochemical properties of cerium(III) coordination polymer with pentafluorobenzoate, Mar. 2022
• T. Nakai; S. Shoji; K. Fushimi; Y. Hasegawa; Y. Kitagawa, 日本化学会第102春季年会, NIR emission of seven-coordinated lanthanide complexes with biphenyl frameworks, Mar. 2022
• S. Hosoya; S. Shoji; K. Fushimi; Y. Kitagawa; Y. Hasegawa, 日本化学会第102春季年会, Synthesis and photophysical properties of Yb(III) coordination polymer with phosphine oxide having porphyrin moiety, Mar. 2022
• M. Harukawa; H. Takano; T. Mita; S. Shoji; K. Fushimi; Y. Kitagawa; Y. Hasegawa, 日本化学会第102春季年会, Synthesis and photophysical properties of a Eu(III) coordination polymer with asymmetric linker, Mar. 2022
• 大清水 海; 庄司 淳; 北川裕一; 長谷川靖哉; 伏見公志, 化学系学協会北海道支部2022年冬季研究発表会, カラー偏光カメラを用いた薄膜のイメージングエリプソメトリー, Jan. 2022
• 比嘉完太; 藤村諒大; 庄司 淳; 北川裕一; 長谷川靖哉; 伏見公志, 化学系学協会北海道支部2022年冬季研究発表会, Si-Mn鋼中の添加元素が不動態に与える影響の解明, Jan. 2022
• 辻湧貴; 庄司 淳; 北川裕一; 長谷川靖哉; 伏見公志, 化学系学協会北海道支部2022年冬季研究発表会, 機械学習を用いた鉄鋼材料表面に形成する腐食生成物の観察, Jan. 2022
• 野村耕作; 庄司 淳; 北川裕一; 長谷川靖哉; 伏見公志, 化学系学協会北海道支部2022年冬季研究発表会, 鋼とAl合金のすき間内部に形成した腐食生成物の膜電位測定, Jan. 2022
• 相川航汰; 北川裕一; 庄司 淳; 伏見公志; 長谷川靖哉, 化学系学協会北海道支部2022年冬季研究発表会, π軌道から4f軌道への電荷移動遷移に基づくカルバゾールEu(III)錯体の感温発光特性, Jan. 2022
• 小西由姫; 庄司 淳; 北川裕一; 伏見公志; 長谷川靖哉, 化学系学協会北海道支部2022年冬季研究発表会, 水圏環境における九核希土類(III)クラスターの感温発光特性, Jan. 2022
• 佐々木建晟; 庄司 淳; 北川裕一; 中村一希; 小林範久; 伏見公志; 長谷川靖哉, 第56回高分子学会北海道支部研究発表会, DNAと結合する希土類配位ナノ粒子, Jan. 2022
• H. Tamiaki; S. Matsubara; S. Shoji, Pacifichem 2021, Self-aggregation of synthetic chlorophyll derivatives as models of natural photosynthetic antenna: their structures, light-harvesting processes, and dynamic construction, Dec. 2021
• 藤村諒大; 庄司 淳; 北川裕一; 長谷川靖哉; 土井教史; 伏見公志, 第68回材料と環境討論会(オンライン), Online ICP-OES測定法の高感度化と鉄系合金の溶出挙動評価, Oct. 2021
• 鶴井 真; 北川裕一; 庄司 淳; 伏見公志; 権 雅行; 田中一生; 長谷川靖哉, 第15回分子化学討論会(オンライン), 相転移によるキラルEu(III)配位高分子のマクロ構造変化と円偏光発光特性, Sep. 2021
• 小西由姫; 庄司 淳; 北川裕一; 伏見公志; 長谷川靖哉, 第71回錯体化学討論会(オンライン), オリゴエチレングリコール鎖を導入した九核希土類(III)クラスターの合成を光機能評価, Sep. 2021
• P. P. Ferreira da Rosa; Y. Kitagawa; S. Shoji; K. Fushimi; Y. Hasegawa, 第71回錯体化学討論会(オンライン), Reversible polymer transformation of luminescent Tb(III) complex, Sep. 2021
• K. Shima; Y. Kitagawa; S. Shoji; K. Fushimi; Y. Hasegawa, 第71回錯体化学討論会(オンライン), Controlling emission lifetime of lanthanide complexes with phenanthrene frameworks, Sep. 2021
• K. Aikawa; Y. Kitagawa; S. Shoji; K. Fushimi; Y. Hasegawa, 2021年光化学討論会(オンライン), Investigation of LMCT excited states on the luminescent properties of Eu(III) complexes with carbazole frameworks, Sep. 2021
• M. Kono; Y. Kitagawa; M. Tsuda; S. Shoji; K. Fushimi; S. Tanaka; Y. Hasegawa, 2021年光化学討論会(オンライン), Activity sensing of cancer cells using luminescent Eu complexes in culture solution, Sep. 2021
• 林 穣; 庄司 淳; 北川裕一; 伏見公志; 長谷川靖哉, 第70回高分子討論会(オンライン), アミド結合を有する発光性Eu(III)配位高分子のガラス状態形成, Sep. 2021
• 佐々木建晟; 庄司 淳; 北川裕一; 中村一希; 小林範久; 伏見公志; 長谷川靖哉, 第70回高分子討論会(オンライン), 希土類配位高分子のナノ粒子化と分子構造変化に伴う発光機能, Sep. 2021
• 相川航汰; 北川裕一; 庄司 淳; 伏見公志; 長谷川靖哉, 第32回配位化合物の光化学討論会(オンライン), π 軌道からf 軌道への電荷移動遷移に基づくカルバゾールEu(III)錯体の発光特性, Aug. 2021
• 佐々木建晟; 庄司 淳; 北川裕一; 中村一希; 小林範久; 伏見公志; 長谷川靖哉, 第32回配位化合物の光化学討論会(オンライン), ベンゾイミダゾール部位を含む希土類配位ナノ粒子の合成と光物性, Aug. 2021
• フェレイラダローサペドロパウロ; 北川裕一; 庄司 淳; 伏見公志; 長谷川靖哉, 第32回配位化合物の光化学討論会(オンライン), ピリジン蒸気による七配位 Tb(III)錯体から八配位 Tb(III)配位高分子の構造変形と光機能, Aug. 2021
• J. Hayashi; S. Shoji; Y. Kitagawa; K. Fushimi; Y. Hasegawa, 16th International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments (SNCPP21) (Online), Synthesis and photophysical properties of amide-bridged Eu(III) coordination polymers, Jun. 2021
• 小西由姫; 庄司 淳; 北川裕一; 伏見公志; 長谷川靖哉, 第32回配位化合物の光化学討論会(オンライン), オリゴエチレングリコール鎖を導入した水溶性テルビウムクラスターの会合体形成と光物性, Aug. 2021
• 島かおり; 北川裕一; 庄司 淳; 伏見公志; 長谷川靖哉, 第37回希土類討論会(オンライン), フェナントレン骨格を導入した蓄光性希土類錯体の機能制御, May 2021
• フェレイラダローサ・ペドロパウロ; 宮崎 栞; 庄司 淳; 北川裕一; 宮田潔志; 赤間知子; 小林正人; 伏見公志; 恩田 健; 武次徹也; 長谷川靖哉, 第37回希土類討論会(オンライン), Eu(III)錯体の七配配位型から八配位への幾何学構造変化に伴う光増感発光増大, May 2021
• 鶴井 真; 北川裕一; 庄司 淳; 伏見公志; 権 雅行; 田中一生; 長谷川靖哉, 第37回希土類討論会(オンライン), 相転移により変化するキラルEu(III)配位高分子の円偏光発光特性, May 2021
• 林 穣; 庄司 淳; 北川裕一; 伏見公志; 長谷川靖哉, 第37回希土類討論会(オンライン), アミド結合を有するEu(III)配位高分子の合成と光物性, May 2021
• 林 穣; 庄司 淳; 北川裕一; 伏見公志; 長谷川靖哉, 第55回高分子学会北海道支部研究発表会, ガラス形成能を有するEu(III)配位高分子の合成と物性, Jan. 2021
• 河野允哉; 庄司 淳; 北川裕一; 伏見公志; 長谷川靖哉, 化学系学協会北海道;年冬季研究発表会;オンライン, ポリエーテル鎖を有するEu(III)錯体の光物性, Jan. 2021
• 林 穣; 庄司 淳; 北川裕一; 伏見公志; 長谷川靖哉, 第69回高分子討論会, 自己会合能を有するEu(III)配位高分子の光物性, Sep. 2020
• M. Kono; S. Shoji; Y. Kitagawa; K. Fushimi; Y. Hasegawa, 2020年web光化学討論会, Luminescence properties of lanthanide complexes with tetraethyleneglycol group, Sep. 2020
• M. Kono; S. Shoji; Y. Kitagawa; K. Fushimi; Y. Hasegawa, 日本化学会第100春季年会, Luminescence properties of Tb(III) complexes introduced tetraethyleneglycol, Mar. 2020
• J. Hayashi; S. Shoji; Y. Kitagawa; T. Seki; H. Ito; K. Fushimi; Y. Hasegawa, 日本化学会第100春季年会, Synthesis and photophysical properties of Eu(III) coordination polymer with amide groups, Mar. 2020
• S. Shoji; P. P. Ferreira da Rosa; Y. Kitagawa; M. Wakeshima; Y. Doi; K. Fushimi; Y. Hasegawa, 日本化学会第100春季年会, Synthesis and photophysical properties of lanthanide(III) complexes with a phosphate ligand having organic radicals, Mar. 2020
• T. Sawanobori; Y. Kitagawa; S. Shoji; I. Hisaki; K. Fushimi; Y. Hasegawa, Annual Meeting of Photochemistry 2019, Syntheses and photophysical properties of Eu(III) coordination polymers built with triphenylene backbones, Sep. 2019
• S. Shoji; H. Tamiaki, The 75th Annual Meeting of The Japan Society of Microscopy, Nanostructures of chlorophyll self-assemblies mimicking light-harvesting antenna systems in photosynthetic green bacteria, Jun. 2019
• S. Shoji; T. Ogawa; S. Matsubara; H. Tamiaki, 15th International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments (SNCPP19), Supramolecular Nanosheets of a Zinc 31-Methoxy Bacteriochlorophyll-d Analog, Jun. 2019
• S. Shoji; T. Ogawa; H. Tamiaki, 日本化学会第99春季年会, Nanosheet of Supramolecular Assembly by a Zinc Chlorophyll Derivative, Mar. 2019
• 庄司 淳; 小川哲也; 民秋 均, 新学術領域「革新的光物質変換」、第2回公開シンポジウム, 亜鉛クロロフィル誘導体の自己会合体による超分子ナノシート, Jan. 2019
• 野村楊作; 庄司 淳; 民秋 均, 新学術領域「革新的光物質変換」第2回公開シンポジウム, 強固なリンカーで連結したクロリン-バクテリオクロリンを利用した光エネルギー捕集型アンテナモデルの構築, Jan. 2019
• S. Shoji; S. Matsubara; H. Tamiaki, 10th Asian Photochmistry Conference (APC2018), Biomimetic self-aggregation of synthetic (bacterio)chlorophylls for photosynthetic light-harvesting antennas, Dec. 2018
• Y. Nomura; S. Shoji; H. Tamiaki, 10th Asian Photochemistry Conference (APC2018), Synthesis of chlorin-bacteriochlorin dyads possessing a rigid linker and construction of light-harvesting antenna models, Dec. 2018
• S. Shoji; M. Wehner; W. Wagner; V. Stepanenko; F. Würthner; H. Tamiaki, 14th International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments (SNCPP18), Self-aggregates of a zinc bacteriochlorophyll-d analog having didodecylamide in the 17-subtstituent, May 2018
• 野村楊作; 庄司 淳; 民秋 均, 日本化学会第97 春季年会、2F4-26/1PC-013, クロロフィル-aとバクテリオクロロフィル-a誘導体を用いたメソ位連結体の合成とその光物性, Mar. 2018
• 民秋 均; 野村楊作; 庄司 淳, 第3回光合成細菌ワークショップ, 緑色細菌アンテナであるクロロゾームのモデル創製と人工光合成への展開, Mar. 2018
• 民秋 均; 松原翔吾; 野村楊作; 庄司 淳, 新学術「革新的光物質変換」第1回公開シンポジウム、O-06, クロロフィル誘導体の自己会合による光捕集アンテナ系の創製, Jan. 2018
• 野村楊作; 庄司 淳; 民秋 均, 新学術「革新的光物質変換」第1回公開シンポジウム、P-8, バクテリオクロロフィル-aアナログをエネルギー受容体として利用した光合成アンテナモデルの構築, Jan. 2018
• 庄司 淳; 民秋 均, 日本生体エネルギー研究会第43回討論会、P17, 緑色光合成細菌をモデルとした超分子型光捕集アンテナ, Dec. 2017
• 野村楊作; 庄司 淳; 民秋 均, 第7回CSJ化学フェスタ、P5-022, バクテリオクロロフィルａアナログを用いた超分子系の構築とその光励起エネルギー移動, Oct. 2017
• 野村楊作; 庄司 淳; 民秋 均, 第29回配位化合物の光化学討論会、P-13, ボロン酸で修飾したバクテリオクロロフィル-ａアナログの合成と物性, Aug. 2017
• Y. Nomura; S. Shoji; H. Tamiaki, International Symposium on Macrocyclic and Supramolecular Chemistry (ISMSC2017), P397, Syntheses and properties of bacteriochlorophyll-a analogs, Jul. 2017
• S. Shoji; H. Tamiaki, International Symposium on Macrocyclic and Supramolecular Chemistry (ISMSC2017), P410, Supramolecular co-aggregates of synthetic zinc chlorophyll derivatives for artificial chlorosomal light-harvesting antenna system, Jul. 2017
• 庄司 淳; 民秋 均, 第15回ホスト・ゲスト超分子化学シンポジウム (SHGSC2017)、A-01, 亜鉛クロロフィル誘導体を用いた共会合体による人工光捕集アンテナの構築, Jun. 2017
• Y. Nomura; S. Shoji; H. Tamiaki, 13th International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments (SNCPP17), P-25, Synthesis of bacteriochlorophyll-a analog and its conjugate with a chlorin, Jun. 2017
• H. Tamiaki; A. Wada; S. Shoji, 2017 International Conference on Artificial Photosynthesis (ICARP2017), IL1-01, Synthesis of zinc 20-substituted bacteriochlorophyll-c analogs and their chlorosomal self-aggregation, Mar. 2017
• S. Shoji; H. Tamiaki, 2017 International Conference on Artificial Photosynthesis (ICARP2017), P1-11, Self-assemblies of synthetic zinc chlorophyll derivatives possessing amide, ester and urea groups at the 17-substituents, Mar. 2017
• 民秋 均; 野村楊作; 庄司 淳, 日本化学会第97春季年会、1C2-50, バクテリオクロリン類の合成とその物性, Mar. 2017
• S. Shoji; H. Tamiaki, 日本化学会第97春季年会, 2PB-108, Synthesis and photophysical properties of heterodyads of zinc and free-base chlorophyll derivatives, Mar. 2017
• S. Shoji; H. Tamiaki, Light-Harvesting Processes 2017 (LHP2017), P34, Supramolecular nanostructures of self-assemblies of bacteriochlorophylls-c and synthetic chlorophyll derivatives, Mar. 2017
• 庄司 淳; 民秋 均, 新学術領域「人工光合成」第5回公開シンポジウム、P-01, クロロゾーム型自己会合体と合成クロロフィルヘテロダイマーによる人工光収穫アンテナの構築, Jan. 2017
• 民秋 均; 庄司 淳, 新学術領域「人工光合成」第5回公開シンポジウム、O-16, クロロゾーム型自己会合体と合成クロロフィルヘテロダイマーによる人工光収穫アンテナの構築, Jan. 2017
• 庄司 淳; 民秋 均, 新学術「人工光合成」若手育成シンポジウム、OP-7, 緑色光合成細菌をモデルとした自己集積型人工光捕集アンテナの構築, Nov. 2016
• S. Shoji; H. Tamiaki, Biohybrid Solar Cell Meeting, T4, Biomimetic nanotubes of self-assembled metal chlorophyll derivatives and observation of their photocurrents, Aug. 2016
• 民秋 均; 庄司 淳, 新学術領域「人工光合成」第５回合同班会議、O-11／P-01, クロロフィル共会合体を用いた人工光捕集アンテナの構築, Aug. 2016
• H. Tamiaki; Y. Nomura; S. Shoji, 21st International Conference on Photochemical Conversion and Storage of Solar Energy (IPS-21), AP1-O1, Artificial light-harvesting antennas using chlorophyll self-aggregates, Jul. 2016
• S. Shoji; H. Tamiaki, 12th International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments (SNCPP16)、P-34, Supramolecular nanotubes of bacteriochlorophylls-c and synthetic metal chlorophyll derivatives, Jun. 2016
• H. Tamiaki; S. Shoji, 第６回フォーラム「人工光合成」, Artificial light-harvesting antennas by chlorophyll self-aggregates, Mar. 2016
• S. Shoji; H. Tamiaki, 日本化学会第96春季年会、3PA-149, Photophysical properties of hetero co-assemblies by chlorophyll self-aggregates and zinc chlorophyll derivatives, Mar. 2016
• 民秋 均; 松原翔吾; 庄司 淳, 日本化学会第96春季年会、3C3-25, ポルフィリン骨格を有するクロロフィル誘導体の合成と自己会合, Mar. 2016
• 庄司 淳; 民秋 均, 新学術領域「人工光合成」第４回公開シンポジウム、P-01, 亜鉛クロロフィル共会合体による人工光収穫アンテナの構築, Jan. 2016
• 民秋 均; 庄司 淳, 新学術領域「人工光合成」第４回公開シンポジウム、O-18, 亜鉛クロロフィル共会合体による人工光収穫アンテナの構築, Jan. 2016
• T. Miyanaga; S. Shoji; Y. Goto; S. Inagaki; H. Tamiaki, 2015環太平洋国際化学会議 (Pacifichem2015)、ENRG 174, Artificial light-harvesting antenna systems as models of chlorosomes using mesoporous silica, Dec. 2015
• H. Tamiaki; S. Shoji, 2015環太平洋国際化学会議 (Pacifichem2015)、ENRG 284, Artificial light-harvesting antenna systems using self-assemblies of semi-synthetic chlorophylls, Dec. 2015
• H. Watanabe; S. Shoji; T. Mizoguchi; H. Tamiaki, 2015環太平洋国際化学会議 (Pacifichem2015)、INOR 1035, Synthesis of bacteriochlorophyll-d amino-analogs and their self-aggregation, Dec. 2015
• 民秋 均; 庄司 淳, 新学術領域「人工光合成」第４回合同班会議、O-17, クロロゾーム型自己集積体と亜鉛クロロフィル誘導体の共会合体による光合成アンテナをモデル系の構築, Jun. 2015
• S. Shoji; H. Tamiaki, 11th International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments (SNCPP15)、O-3, Chlorosomal Self-Assemblies with Synthetic Chlorophyll Derivatives and Their Properties for Artificial Light-Harvesting Antenna Systems, May 2015
• S. Shoji; H. Tamiaki, 1st International Solar Fuels Conference Young (ISF-Young)、M-43, Supramolecules of chlorosomal self-aggregates with zinc chlorophyll derivatives on a quartz for artificial light-harvesting antennas, Apr. 2015
• S. Shoji; H. Tamiaki, 1st International Solar Fuels Conference (ISF-1)、F:Po-6, Chlorosomal self-assemblies with co-aggregative zinc chlorophyll derivatives for artificial light-harvesting antennas, Apr. 2015
• 宮永拓弥; 庄司 淳; 後藤康友; 稲垣伸二; 民秋 均, 日本化学会第95春季年会、3J3-10, メソポーラスシリカ内での亜鉛クロロフィル誘導体の自己会合, Mar. 2015
• 庄司 淳; 民秋 均, 日本化学会第95春季年会、3J3-11, 亜鉛クロロフィル誘導体を用いたクロロゾーム型クロロフィル自己集積体との超分子形成, Mar. 2015
• S. Shoji, NUS-Rits Bilateral Symposium on Functional π-Conjugated Molecules, Self-aggregates of synthetic chlorophyll derivatives for artificial chlorosomal light-harvesting antenna, Jan. 2015
• 宮永拓弥; 庄司 淳; 後藤康友; 稲垣伸二; 民秋 均, 新学術領域「人工光合成」第３回公開シンポジジウム、P-01, メソポーラスシリカ内で自己会合体を形成した亜鉛クロロフィル誘導体の物性, Jan. 2015
• S. Shoji; H. Tamiaki, 2014 International Conference on Artificial Photosynthesis (ICARP2014)、P1-15, Supramolecules with chlorosomal self-aggregates for artificial photosynthetic light-harvesting antennas, Nov. 2014
• T. Miyanaga; S. Shoji; Y. Goto; S. Inagaki; H. Tamiaki, 2014 International Conference on Artificial Photosynthesis (ICARP2014)、P1-20, Development of artificial light-harvesting antenna systems using mesoporous silica mimicking chlorosomes, Nov. 2014
• 北川裕一; 庄司 淳; 伊佐治恵; 石井和之; 民秋 均, 2014年光化学討論会、1A18, 異方性円偏光二色性を用いたキラルＪ会合体の構造解析法に関する検討, Oct. 2014
• 庄司 淳; 民秋 均, 2014年光化学討論会、3P020, クロロゾーム型チューブ状亜鉛クロロフィル自己集積体の物性, Oct. 2014
• S. Shoji; H. Tamiaki, 5thEuCheMS、P-F3-003, Tube-shaped supramolecular nanostructures of self-aggregates of cadmium, magnesium and zinc chlorophyll derivatives, Sep. 2014
• 宮永拓弥; 庄司 淳; 民秋 均, 第25回基礎有機化学討論会、2P078, 長鎖アルキル基を有する亜鉛クロロフィル誘導体の合成と自己会合, Sep. 2014
• 宮永拓弥; 庄司 淳; 後藤康友; 稲垣伸二; 民秋 均, 新学術領域「人工光合成」第３回合同班会議、P01, 光合成アンテナをモデルとしたメソポーラスシリカ上での亜鉛クロロフィル誘導体の自己会合体の構築, Aug. 2014
• T. Miyanaga; S. Shoji; Y. Goto; S. Inagaki; H. Tamiaki, XXVth IUPAC Symposium on Photochemistry、P248, Self-aggregation of zinc chlorophyll derivatives possessing long alkyl chain on mesoporous silica, Jul. 2014
• H. Tamiaki; T. Miyanaga; S. Shoji, 8th International Conference on Porphyrins and Phthalocyanines (ICPP-8)、#15-3, Self-aggregation of semi-synthetic chlorophyll derivatives and their supramolecular structures, Jun. 2014
• T. Miyanaga; S. Shoji; Y. Goto; S. Inagaki; H. Tamiaki, 10th International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments (SNCPP14)、P-13, Self-Aggregation Behavior of Zinc Chlorophyll Derivatives on Mesoporous Silica, May 2014
• 庄司 淳; 宮永拓弥; 後藤康友; 稲垣伸二; 民秋 均, 新学術領域「人工光合成」第4回フォーラム、P-07, 光合成アンテナをモデルとしたメソポーラスシリカ上での亜鉛クロロフィル自己集積体の構築, Mar. 2014
• 民秋 均; 島崎翔平; 庄司 淳, 日本化学会第94春季年会、2G2-08, クロロフィルc1誘導体の合成とその会合挙動, Mar. 2014
• 民秋 均; 宮永拓弥; 庄司 淳, 日本化学会第94春季年会、2G2-09, 亜鉛クロロフィル誘導体の合成とメソポーラスシリカ上での自己会合挙動, Mar. 2014
• 民秋 均; 中村隆宏; 庄司 淳, 日本化学会第94春季年会、2G2-10, クロリン-ポルフィリン連結体の合成と光物性, Mar. 2014
• 北川裕一; 庄司 淳; 伊佐治恵; 石井和之; 民秋 均, 錯体化学会第63回討論会、2PB-019, 異方性円偏光二色性を用いたキラル超分子の構造解析法に関する検討, Nov. 2013
• 庄司 淳; 宮永拓弥; 民秋 均, 新学術領域「人工光合成」第2回公開シンポジウム、P-01, 光合成アンテナをモデルとしたチューブ状クロロフィル超分子ナノ構造体の構築と固体表面上での自己集積, Oct. 2013
• K. Sadaoka; S. Shoji; Y. Tsukatani; T. Yoshitomi; H. Tamiaki; Y. Saga, 15th European Society for Photobiology Congress、P083, Demetalation properties of chlorophyll c isolated from the diatom Chaetoceros calcitrans, Sep. 2013
• 庄司 淳; 民秋 均, 第24回基礎有機化学討論会、2P24, 自己集積型亜鉛クロロフィル誘導体の合成と物性, Sep. 2013
• 庄司 淳; 民秋 均, 2013年光化学討論会、3C02, 亜鉛クロロフィル自己集積体の超分子ナノ構造とその物性, Sep. 2013
• 庄司 淳; 民秋 均, 第７回バイオ関連化学シンポジウム、3A-02, 緑色光合成細菌の光補集系をモデルとした人工チューブ状クロロフィル自己集積体の構築, Sep. 2013
• S. Shoji; H. Tamiaki, Light-harvesting Satellite Meeting 2013 (LH2013)、D4/D-29, Tube-shaped self-aggregates of natural bacteriochlorophylls and their synthetic models, Aug. 2013
• 庄司 淳; 溝口 正; 民秋 均, 第21回光合成セミナー、O-8, 天然バクテリオクロロフィル-ｃとそのモデル分子によるチューブ状自己会合体の構築, Jul. 2013
• 定岡香菜; 廣田圭耶; 庄司 淳; 塚谷祐介; 吉冨太一; 民秋 均; 佐賀佳央, 第21回光合成セミナー、P-1, Chaetoceros gracilisから単離したクロロフィルｃの脱金属反応特性, Jul. 2013
• 民秋 均; 庄司 淳; 溝口 正, 新学術領域「人工光合成」第2回合同班会議、P1, 天然産バクテリオクロロフィルｃによる針状自己集積体の構築, Jun. 2013
• S. Shoji; T. Hashishin; H. Tamiaki, International Symposia on Advancing the Chemical Sciences: Challenges in Organic Materials and Supramolecular Chemistry (ISACS10)、P-95, Supramolecular Nanostructures of Self-Aggregative Chlorophyll Derivatives Possessing Amide Group(s) at the 17-propionate Residue, Jun. 2013
• S. Shoji; T. Hashishin; H. Tamiaki, 9th International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments (SNCPP13)、P-28, Tubular Supramolecules of Natural Bacteriochlorophylls-c and Their Synthetic Analogs, Jun. 2013
• 庄司 淳; 溝口 正; 民秋 均, 日本化学会第93春季年会、3D5-15, 天然産バクテリオクロロフィル自己会合体の超分子ナノ構造, Mar. 2013
• 高山ももこ; 西野優里; 沼田宗典; 民秋 均; 庄司 淳, 日本化学会第93春季年会、2PC-127, マイクロ集積場の時空間制御による新規ヘテロ接合技術の開発, Mar. 2013
• 庄司 淳; 溝口 正; 民秋 均, 分子ナノシステムの創発化学 領域終了シンポジウム、P-25, 天然産バクテリオクロロフィル類による針状超分子集合体の構築, Feb. 2013
• S. Shoji; T. Hashishin; T. Mizoguchi; H. Tamiaki, NCTU-RU Bilateral Symposium on Organic Photoactive Materials, Supramolecular nanostructures of self-aggregates of natural bacteriochlorophylls and semi-synthetic chlorophyll derivatives, Jan. 2013
• S. Shoji; T. Mizoguchi; H. Tamiaki, 2nd International Symposium on Biosynthesis of Tetrapyrroles (BSTP12)、ST-1, Reconstruction of Self-Aggregates of Natural Bacteriochlorophyll-c Mixture and Their Microscopic Observation, Dec. 2012
• 民秋 均; 庄司 淳, 分子ナノシステムの創発化学第４回全体会議、O-19/P-22, 半合成クロロフィル類による針状超分子集合体の構築, Aug. 2012
• 柏山祐一郎; 横山亜紀子; 木下雄介; 庄司 淳; 宮下英明; 白鳥峻志; 菅 寿美; 石川可奈子; 石川 輝; 石田健一郎; 藤沼大幹; 青木啓介; 小林正美; 野本信也; 溝口 正; 民秋 均, 日本藻類学会第36回大会、B21, 微細藻類捕食プロティストによるクロロフィルの解毒代謝, Jul. 2012
• S. Shoji; T. Hashishin; H. Tamiaki, 8th International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments (SNCPP12)、P26, Supramolecular Nanostructures of Synthetic Bacteriochlorophyll-d Analogs Possessing Various Substituents, Jun. 2012
• 高山ももこ; 沼田宗典; 民秋 均; 庄司 淳, 第9回ホスト・ゲスト化学シンポジウム、2P-25, マイクロフロー空間内の動的界面を用いた超分子構造の制御, May 2012
• 庄司 淳; 宇佐美久尚; 民秋 均, 日本化学会第92春季年会、1D2-03, ロッド状亜鉛クロロフィル自己集積体における光電流発生, Mar. 2012
• 高山ももこ; 沼田宗典; 民秋 均; 庄司 淳, 日本化学会第92春季年会、1H5-24, 動的界面を用いた新規分子集積システムの構築, Mar. 2012
• 民秋 均; 庄司 淳, 分子ナノシステムの創発化学第３回公開シンポジウム、P-22, 合成クロロフィルによるロッド状超分子集合体の構築, Feb. 2012
• 高山ももこ; 沼田宗典; 民秋 均; 庄司 淳, 分子ナノシステムの創発化学第３回公開シンポジウム、P-25, 動的界面を用いた新規分子集積法の開発, Feb. 2012
• S. Shoji, Rits-HKUST Joint Seminar, Construction of artificial chlorosomal light-harvesting antenna using synthetic zinc chlorophyll derivatives on any substrates, Jan. 2012
• H. Tamiaki; S. Shoji, The 3rd International Forum on Photoenrgy Future (IFPFO2011)、Lecture 14, Photocurrent of synthetic chlorophyll derivatives on electrodes: Development of chlorophyll-sensitized solar cells, Dec. 2011
• 庄司 淳; 民秋 均, 第23回 配位化合物の光化学討論会、P-10, クロロフィル金属錯体を用いたロッド状自己集積体の構築とその光物性, Aug. 2011
• S. Shoji; T. Hashishin; H. Tamiaki, Gordon-Kenan Research Seminar on Photochemistry, Self-aggregation of synthetic bacteriochlorophyll-d analogs possessing various substituents as a model of chlorosomal antenna, Jul. 2011
• S. Shoji; T. Hashishin; H. Tamiaki, Gordon Research Conference on Photochemistry, Rod-like self-aggregation of synthetic bacteriochlorophyll-d analogs and observation of their photocurrents, Jul. 2011
• S. Shoji; T. Hashishin; H. Tamiaki, 7th International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments (SNCPP11)、S-2/P33, Construction of Artificial Chlorosomal Antenna from a Synthetic Bacteriochlorophyll-d Analog and Observation of Their Photocurrents, Jun. 2011
• 庄司 淳; 橋新 剛; 民秋 均, 日本化学会第91春季年会、1B5-28, 亜鉛クロロフィル誘導体の合成と基板上でのそれらの自己集積, Mar. 2011
• S. Shoji; T. Hashishin; H. Tamiaki, 2010環太平洋国際化学会議(Pacifichem2010)、MATL-752, Self-aggregates of synthetic bacteriochlorophyll-d analogs and their supramolecular nanostructures, Dec. 2010
• 庄司 淳; 橋新 剛; 民秋 均, 第29回固体・表面光化学討論会、120, 基板上でのクロロフィル会合体のナノ構造と光応答, Nov. 2010
• H. Tamiaki; S. Shoji, 第15回国際光合成会議サテライト集会「アンテナと反応中心」、S6-5, Chlorosomal self-aggregates of synthetic bacteriochlorophyll-d analogs possessing various substituents at the D-ring, Aug. 2010
• H. Tamiaki; S. Shoji; M. Kunieda, 6th International Conference on Porphyrins and Phthalocyanines (ICPP-6)、S05-P-014, Self-aggregates of synthetic bacteriochlorophyll-d analogs possessing an oligomethylene chain at the 17-propionate residue, Jul. 2010
• S. Shoji; T. Hashishin; H. Tamiaki, 6th International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments (SNCPP10)、P26, Microscopic Analyses of Supramolecular Nanostructures of Bacteriochlorophyll-d Analog Self-Aggregates, Jun. 2010
• 民秋 均; 庄司 淳; 國枝道雄; 沼田宗典; 波多野 吏, 日本化学会第90春季年会、2B3-11, オリゴメチレン鎖を有するクロロフィル誘導体の合成とその自己会合特性の評価, Mar. 2010
• S. Yasuda; M. Tanaka; A. Tsuruta; T. Hagiwara; S. Shoji; Y. Mikata, Eighteenth International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments (SNCPP23), Design of fluorescent cadmium ion sensor by introducing methoxy groups into bisquinolin-based tetradentate ligand which exhibit zinc ion selectivity, Poster presentation, Jun. 2023
• M. Nagaoka; K. Kawakami; S. Shoji; Y. Mikata, Eighteenth International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments (SNCPP23), Cadmium-selective fluorescence response of bisquinoline-type tetradentate ligand with o-phenylenediamine skeleton, Poster presentation, Jun. 2023
• Y. Kitagawa; T. Nakai; K. Shima; M. Wang; S. Shoji; K. Fushimi; Y. Hasegawa, Eighteenth International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments (SNCPP23), Bright luminescent lanthanide complexes with π-conjugated polycyclic aromatic ligands, Poster presentation, Jun. 2023
• S. Shoji, Eighteenth International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments (SNCPP23), Near infrared luminescent supramolecular cage with porphyrin and lanthanide complexes, Invited oral presentation, Jun. 2023
• 高野夏美; 藤村諒大; 庄司 淳; 北川裕一; 長谷川靖哉; 中川凌吾; 尾﨑良太; 伏見公志, 材料と環境2023, アルミニウム合金ろう付接合部の腐食挙動とろう材へのZnと Cu添加の影響, Jun. 2023
• 藤村諒大; 庄司 淳; 北川裕一; 長谷川靖哉; 伏見公志, 材料と環境2023, 水溶液中の鉄系材料表面におけるアノード反応メカニズムの検討, Jun. 2023
• 水尻雄也; 庄司 淳; 北川裕一; 長谷川靖哉; 伏見公志, 材料と環境2023, 透過水素および非侵入その場測定による鉄鋼中の補足水素量の検討, Jun. 2023
• 中井拓真; 庄司 淳; 中西貴之; 伏見公志; 長谷川靖哉; 北川裕一, 第39回希土類討論会, 配位子の長寿命トリプレット状態を利用したYb(III)-Lu(III)混合結晶の高感度酸素センシング, May 2023
• 富川虎乃輔; 庄司 淳; 赤間知子; 小林正人; 伏見公志; 中西貴之; 武次徹也; 長谷川靖哉; 北川裕一, 第39回希土類討論会, β-ジケトナート配位子を有するセリウム錯体の電荷移動発光, May 2023
• 林穣; 庄司 淳; 北川裕一; 伏見公志; 長谷川靖哉, 第39回希土類討論会, 三重らせん型Eu(III)配位高分子の合成と配位挙動, May 2023
• 春川美友; 髙野秀明; 美多 剛; 庄司 淳; 伏見公志; 北川裕一; 長谷川靖哉, 第39回希土類討論会, 架橋配位子への置換基導入による発光性Eu(III)配位高分子の感温機能挙動, May 2023
• J. Hayashi; S. Shoji; Y. Kitagawa; K. Fushimi; Y. Hasegawa, 錯体化学会第72回討論会, Synthesis and photophysical properties of Eu(III) coordination polymers with amide units, Sep. 2022
• 春川美友; 髙野秀明; 美多 剛; 庄司 淳; 伏見公志; 北川裕一; 長谷川靖哉, 錯体化学会第72回討論会, 電子供与および電子求引性置換基を架橋配位子に導入したEu(III)配位高分子の発光機能, Sep. 2022
• 細谷祥太; 庄司 淳; 伏見公志; 北川裕一; 長谷川靖哉, 錯体化学会第72回討論, ポルフィリン-Yb(III)四核ケージ状錯体の光増感発光, Sep. 2022
• M. Tsurui; Y. Kitagawa; S. Shoji; K. Fushimi; Y. Hasegawa, 錯体化学会第72回討論会, Circularly polarized luminescence of Eu(III) coordination polymers with distorted chiral moieties, Sep. 2022
• Y. Konishi; S. Shoji; Y. Kitagawa; K. Fushimi; Y. Hasegawa, 錯体化学会第72回討論会, Thermo-sensitive luminescence of nano-nuclear Ln(III) clusters with tetraethylene glycol monomethyl ether chains, Sep. 2022
• T. Tomikawa; S. Shoji; T. Akama; M. Kobayashi; K. Fushimi; T. Taketsugu; Y. Hasegawa; Y. Kitagawa, 2022年光化学討論会, tabilization of 4f-π* charge transfer excited state for Ce(III) complexes and their luminescent propertie, Sep. 2022
• T. Nakai; S. Shoji; K. Fushimi; Y. Hasegawa; Y. Kitagawa, 2022年光化学討論会, Ultra-high sensitive oxygen sensor using delayed emission of molecular Yb(III)-Lu(III) crystals, Sep. 2022
• K. Aikawa; S. Shoji; K. Fushimi; Y. Hasegawa; Y. Kitagawa, 2022年光化学討論会, π-4f charge transfer emission of Eu(III) complexes with strong donor typed ligands, Sep. 2022
• M. Wang; M. Kono; S. Shoji; Y. Kitagawa; K. Fushimi; M. Tsuda; S. Tanaka; Y. Hasegawa, 2022年光化学討論会, Cancer cell activity analysis using luminescent Eu(III) complexes, Sep. 2022
• T. Tomikawa; S. Shoji; T. Akama; M. Kobayashi; K. Fushimi; T. Taketsugu; Y. Hasegawa; Y. Kitagawa, Seventeenth International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments (SNCPP22), MLCT emission of Ce(III) coordination polymer induced by low HOMO energy of ligand, Jun. 2022
• Oxygen sensing; properties of seven-coordinated lanthanide complex with biphenyl framework, Seventeenth International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments (SNCPP22), T. Nakai, S. Shoji, K. Fushimi, Y. Hasegawa, Y. Kitagawa, Jun. 2022
• S. Hosoya; S. Shoji; K. Fushimi; Y. Kitagawa; Y. Hasegawa, Seventeenth International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments (SNCPP22), Near-infrared emission and singlet oxygen generation of an Yb(III) tetranuclear complex with porphyrin photosensitizer, Jun. 2022
• M. Harukawa; H. Takano; T. Mita; S. Shoji; K. Fushimi; Y. Kitagawa; Y. Hasegawa, Seventeenth International Workshop on Supramolecular Nanoscience of Chemically Programmed Pigments (SNCPP22), Synthesis and photophysical properties of a Eu(III) coordination polymer with unsymmetric linker, Jun. 2022
• 藤村諒大; 庄司 淳; 北川裕一; 長谷川靖哉; 土井教史; 伏見公志, 電気化学会北海道支部第36回ライラックセミナー・第26回若手研究者交流会, 高い時間応答感度を有するin-situ ICP-OES測定用電気化学セルの開発と適用, Jun. 2021
• 柳本はるの; 庄司 淳; 北川裕一; 長谷川靖哉; 伏見公志, 材料と環境2021(オンライン), 白金微小電極を用いた溶液の局所酸性化と鉄表面の硫化反応解析, May 2021
• 庄司 淳, 立命館大学 ライスボールセミナー, 緑色光合成細菌をモデルとした人工的な光合成アンテナ系の構築, Nov. 2014
• 富川虎乃輔; 相川航汰; ワン メンフィ; 庄司 淳; 赤間知子; 小林正人; 伏見公志; 中西貴之; 武次徹也; 長谷川靖哉; 北川裕一, 第13回CSJ化学フェスタ2023, 希土類錯体のf軌道に基づく新しい発光機能の探索, Poster presentation, Oct. 2023
• 細谷祥太; 庄司 淳; 伏見公志; 小林正人; 中西貴之; 北川裕一; 武次徹也; 長谷川靖哉, 第13回CSJ化学フェスタ2023, Yb(III)とポルフィリンで構成された近赤外発光性Metal-Organic-Cageによる分子認識, Poster presentation, Oct. 2023
• 板谷康佑; 鶴井 真; ワン メンフィ; 庄司 淳; 伏見公志; 長谷川靖哉; 北川裕一, 第13回CSJ化学フェスタ2023, 強い円偏光発光を示すキラルEu(III)錯体のエネルギー移動を利用した偏光度制御, Poster presentation, Oct. 2023
• 春川美友; ワン メンフィ; 庄司 淳; 伏見公志; 北川裕一; 長谷川靖哉, 第13回CSJ化学フェスタ2023, 希土類配位高分子に導入した二種連結配位子の混合比変調による発光機能制御, Poster presentation, Oct. 2023
• 中井拓真; ワン メンフィ; 庄司 淳; 中西貴之; 伏見公志; 長谷川靖哉; 北川裕一, 第13回CSJ化学フェスタ2023, 錯体間エネルギー移動を利用した希土類錯体結晶の発光寿命制御と酸素センシング機能の創出, Poster presentation, Oct. 2023
• T. Tomikawa; M. Wang; S. Shoji; T. Akama; M. Kobayashi; K. Fushimi; T. Nakanishi; T. Taketsugu; Y. Hasegawa; Y. Kitagawa, 錯体化学会第73回討論会, An f-p* charge transfer emission of b-diketonato cerium complexes, Oral presentation, Sep. 2023
• S. Hosoya; S. Shoji; T. Nakanishi; M. Kobayashi; K. Fushimi; Y. Kitagawa; T. Taketsugu; Y. Hasegawa, 錯体化学会第73回討論会, Molecular recognition system based on NIR luminescent metal-organic-cage with Yb(III) and porphyrin, Oral presentation, Sep. 2023
• 榎戸雅基; 王 夢菲; 庄司 淳; 伏見公志; 北川裕一; 長谷川靖哉, 錯体化学会第73回討論会, Eu(III)錯体のアミノ酸誘導体に起因した円偏光発光特性, Poster presentation, Sep. 2023
• 庄司 淳; 細谷祥太; 中西貴之; 小林正人; 伏見公志; 北川裕一; 武次徹也; 長谷川靖哉, 第33回基礎有機化学討論会, ポルフィリンとYb(III)錯体を連結したカゴ状超分子の分子認識と発光特性, Oral presentation, Sep. 2023
• T. Nakai; M. Wang; S. Shoji; T. Nakanishi; K. Fushimi; Y. Hasegawa; Y. Kitagawa, 2023年光化学討論会, Ultra-highly Sensitive Oxygen Sensing Properties of Mixed Yb(III)-Lu(III) Crystals Through Intermolecular Energy Transfer, Oral presentation, Sep. 2023
• K. Itaya; M. Tsurui; M. Wang; S. Shoji; K. Fushimi; Y. Hasegawa; Y. Kitagawa, 2023年光化学討論会, Circularly Polarized Luminescence of Phenanthrene Eu(III) Complexes Depending on Energy Transfer Pathways, Poster presentation, Sep. 2023
• M. Tsurui; Y. Kitagawa; M. Wang; S. Shoji; K. Fushimi; Y. Hasegawa, 11th International Conference on f-Element (ICFE), Circularly polarized luminescence and charge transfer characteristics of chiral Eu(III) coordination polymers, Poster presentation, Aug. 2023
• J. Hayashi; M. Wang; S. Shoji; Y. Kitagawa; K. Fushimi; Y. Hasegawa, 11th International Conference on f-Element (ICFE), Photophysical properties of amide-bridged Eu(III) coordination polymers, Poster presentation, Aug. 2023
• 富川虎乃輔; ワン メンフィ; 庄司 淳; 赤間知子; 小林正人; 伏見公志; 中西貴之; 武次徹也; 長谷川靖哉; 北川裕一, 第34回配位化合物の光化学討論会, ヘキサフルオロアセチルアセトナートを有するセリウム錯体の電荷移動発光, Poster presentation, Aug. 2023
• 板谷康佑; 鶴井 真; ワン メンフィ; 庄司 淳; 伏見公志; 長谷川靖哉; 北川裕一, 第34回配位化合物の光化学討論会, 二種の光増感剤を有するEu(III)錯体のエネルギー移動経路に依存した円偏光発光特性, Poster presentation, Aug. 2023
• 春川美友; ワン メンフィ; 庄司 淳; 伏見公志; 北川裕一; 長谷川靖哉, 第34回配位化合物の光化学討論会, 二種の連結配位子の混合比変調によるEu(III)配位高分子の発光機能, Oral presentation, Aug. 2023
• M. Tsurui; Y. Kitagawa; M. Wang; S. Shoji; K. Fushimi; Y. Hasegawa, The 31st International Conference on Photochemistry (ICP), Circularly polarized luminescence of chiral Eu(III) coordination polymers with ligand field strain, Poster presentation, Jul. 2023
• 庄司 淳, 錯体化学若手の会近畿支部大65回支部勉強会, 光合成の色素に着目した機能性分子の創製, Invited oral presentation, Dec. 2023
• Y. Mizushiri; M. Iwai; S. Kitano; S. Shoji; Y. Kitagawa; Y. Hasegawa; S. Hayashi; H. Habasaki; K. Fushimi, International Conference on Surface Engineering (ICSE2023), Quantitative Evaluation of Hydrogen Intruded into Steel Sheet during Devanathan-Stachurski Experiments, Poster presentation, Nov. 2023
• K. Fushimi; K. Ooshimizu; S. Shoji; Y. Kitagawa; Y. Hasegawa, International Conference on Surface Engineering (ICSE2023), Development of imaging ellipsometry using a polarized camera for in-situ analysis of oxidizing steel surface, Oral presentation, Nov. 2023
• A. Fujimura; S. Shoji; Y. Kitagawa; Y. Hasegawa; T. Doi; K. Fushimi, The Annual Congress of the European Federation of Corrosion (EUROCORR2023), Electrode reaction kinetics and mechanisms on Fe-based alloys using electrochemical online ICP-OES, Poster presentation, Aug. 2023
• K. Fushimi; Y. Mizushiri; S. Shoji; Y. Kitagawa; Y. Hasegawa, The Annual Congress of the European Federation of Corrosion (EUROCORR2023), Quantitative measurement of hydrogen intruded in steel sheet by channel flow double electrode with Devanath-Stachurski cell, Oral presentation, Aug. 2023
• 水尻雄也; 庄司 淳; 北川裕一; 長谷川靖哉; 伏見公志, 日本鉄鋼協会第185回春季講演大会, 非侵入性水素その場検出による鉄鋼材料中の試料内水素量の検討, Mar. 2023
• S. Shoji; S. Hosoya; K. Inage; Y. Kitagawa; Y. Hasegawa, 5th ICReDD International Symposium, Supramolecular Structures of Yb(III) Coordination Compounds with Bidentate and Tetradentate Porphyrin Ligands, Jan. 2023
• S. Shoji; S. Hosoya; Y. Kitagawa; Y. Hasegawa, 4th ICReDD International Symposium, NIR emission of a Yb(III) tetranuclear complex with porphyrin photosensitizer, Mar. 2022
• 小池 陽; 内田瑞歩; 庄司 淳; 三方裕司, 錯体化学会第73回討論会, キノリン類縁体を有するアミノエタノール型五座配位子により支持された銅単核錯体の構造と電子状態制御, Poster presentation, Sep. 2023
• 明渡美結; 濵本絵里奈; 吉田祥子; 庄司 淳; 三方裕司, 錯体化学会第73回討論会, キノリン類縁体を有するBn-TPEN型五座配位子を用いた銅単核錯体の構造と電子状態, Poster presentation, Sep. 2023
• 板谷康佑; 鶴井 真; ワン メンフィ; 庄司 淳; 伏見公志; 長谷川靖哉; 北川裕一, 錯体化学若手の会北海道支部勉強会, キラルEu(III)錯体の円偏光発光におけるエネルギー移動経路依存性, Poster presentation, Nov. 2023
• 三方裕司; 登坂菜生; 安田早織; 櫻井優衣; 庄司 淳, 第21回ホスト-ゲスト・超分子化学シンポジウム(SHGSC2024), メトキシ基を有するビスキノリン型四座配位子を用いたカドミウムイオンの特異的蛍光検出, Jun. 2024
• 安田早織; 萩原妙佳; 庄司 淳; 三方裕司, 第21回ホスト-ゲスト・超分子化学シンポジウム(SHGSC2024), イソプロピル基を導入したビスキノリン型四座配位子のカドミウム特異的蛍光応答, Jun. 2024
• 庄司 淳; 稲毛康太; 森 咲樹; 北川裕一; 伏見公志; 北山 隆; 三方裕司; 長谷川靖哉, 第21回ホスト-ゲスト・超分子化学シンポジウム(SHGSC2024), 希土類錯体を連結部位に用いたスタック型ポルフィリン超分子二量体の合成と物性, Jun. 2024
• 富川虎之輔; 庄司 淳; ワン メンフィ; 赤間知子; 斉田謙一郎; 小林正人; 伏見公志; 中西貴之; 武次徹也; 長谷川靖哉; 北川裕一, 第40回希土類討論会, β-ジケトナート配位子を有するセリウム錯体の電荷移動発光と理論的解析, May 2024
• 明渡美結; 濱本絵里奈; 吉田祥子; 庄司 淳; 三方裕司, 錯体化学会第74回討論会, 含窒素芳香族部位を有するエチレンジアミン型五座配位子を含むどう(II)単核錯体の構造と電気化学的特性, Sep. 2024

Awards

• 第7回北大部局横断シンポジウム 部局横断型若手研究助成事業金賞, Oct. 2021
• 第6回北大部局横断シンポジウム 部局横断型若手研究助成事業奨励賞, Oct. 2020
• International Conference on Artificial Photosynthesis, Excellent Poster Award, Nov. 2014
• 立命館大学博士研究発表会 優秀賞, Mar. 2014
• CSJ Student Presentation Award, The Chemical Society of Japan, Apr. 2013
• 立命館大学生命科学部応用化学コース 修士論文優秀賞, Mar. 2012

Industrial Property Rights

• Patent right, 希土類錯体、発光材料、光増感剤、及び酸素センサー, 庄司 淳, 細谷祥太, 長谷川靖哉, 北川裕一, 伏見公志, 特願2022-035633, 08 Mar. 2022
• Patent right, 新規Ce系青色発光材料, 北川裕一, 富川虎乃輔, 庄司 淳, 長谷川靖哉, 伏見公志, 赤間知子, 小林正人, 武次徹也, 特願2022-035630, 08 Mar. 2022
• Patent right, 発光材料、酸素センサー、および塗料, 北川裕一, 中井拓真, 島かおり, 庄司 淳, 長谷川靖哉, 特願2022-033536, 04 Mar. 2022
• Patent right, 結晶接合体及びその製造方法, 長谷川靖哉, フェレイラ ダ, ローサ, ペドロ パウロ, 北川裕一, 庄司 淳, 伏見公志, 特願2022-007199, 20 Jan. 2022
• Patent right, 希土類錯体、発光材料、発光体、及び、ホスフィンオキシド基を有する化合物, 長谷川靖哉, 林 穣, 北川裕一, 庄司 淳, 伏見 公志, 特願2021-074135, 26 Apr. 2020

Research Projects

• Grant-in-Aid for Scientific Research (B), Apr. 2022, Mar. 2026, 22H02152, Coinvestigator, ミセル反応場で合成する希土類配位ナノ粒子の構造制御と光機能材料化, 長谷川 靖哉; 北川裕一; 庄司淳, Japan Society for the Promotion of Science, Grants-in-Aid for Scientific Research Grant-in-Aid for Scientific Research (B), Hokkaido University, 17420000, 13400000, 4020000, kaken

  対象リソースIRI
• Grant-in-Aid for Early-Career Scientists, Apr. 2022, Mar. 2025, 22K14741, Principal investigator, ポルフィリンと希土類の配位高分子による光線力学ナノセラノスティクス材料の創成, 庄司 淳, Japan Society for the Promotion of Science, Grants-in-Aid for Scientific Research Grant-in-Aid for Early-Career Scientists, Hokkaido University, 4550000, 3500000, 1050000, kaken

  対象リソースIRI
• Nov. 2021, Mar. 2022, Principal investigator, 外部環境に応答する近赤外発光性ポルフィリン希土類錯体の開発, 令和3年度FCC若手フィージビリティ・スタディ支援経費
• Oct. 2021, Mar. 2022, Principal investigator, 緑色発光希土類錯体の透明化と植物成長に与える影響の評価, Hokkiado University, Formation of collaboration among young researchers for frontier sciences, 1000000
• May 2021, Mar. 2022, Coinvestigator, Sensing techniques using lanthanide emission as information medium, Yuichi Kitagawa; Sunao Shoji, Japan Science and Technology Agency, JST A-STEPトライアウトタイプ
• Oct. 2020, Mar. 2021, Principal investigator, 赤色発光希土類錯体を用いた透明な波長変換資材による植物育成, Hokkaido University, Cross-departmental Young Researcher Grants of Hokkaido University, 550000
• 2019, 2020, Principal investigator, クロロフィル集積体のナノ構造に関する研究, 庄司 淳, The Japan Science Society, Sasakawa Scientific Research Grant, Hokkaido University, 700000
• Grant-in-Aid for JSPS Fellows, Apr. 2014, Mar. 2016, 14J08467, 人工光捕集アンテナを基盤とした光機能性超分子ナノデバイスの創製, 庄司 淳, Japan Society for the Promotion of Science, Grants-in-Aid for Scientific Research Grant-in-Aid for JSPS Fellows, Ritsumeikan University, 2170000, 1900000, 270000, 緑色光合成細菌の光合成器官を模倣し、人工的な光捕集・伝達に優れた光機能性超分子ナノ構造体を構築し、その機能解明やデバイス開発を行うことを本研究の目的としている。平成27年度は、クロロフィル誘導体を用い、(1)クロロゾーム型ロッド状自己集積体(SA)の光機能評価、(2)サイズ制御、(3)他色素との複合化、(4)光機能性超分子ナノデバイスの評価を行った。以下にその詳細を記す。 1.ロッド状SAの光機能評価：ロッド状SAの励起エネルギー移動過程は、分光測定やモデル計算が行われただけで、それ自体を顕微分光した例はない。ロッド状SAの顕微分光を行うために、ガラス基板を疎水化し、ロッド状SAの固定化と安定化を試みた。真空・低温下で蛍光測定を行うことで、サブマイクロメーターのSAの蛍光像が観察可能であった。 2.サイズ制御：昨年度に見出したSAの成長を阻害しうるクロロフィル分子を用い、顕微鏡によるロッド状SAのナノ構造の観察を行った。均一なサイズのロッド状SAは形成せず、ロッド状SAは強い分子間相互作用により成長することが明らかとなった。 3.他色素との複合化：ロッド状SAと他の色素分子を組み合わせることで、光機能に優れた超分子構造体の構築を目指した。昨年度に見出した亜鉛バクテリオクロロフィル-a誘導体に加え、亜鉛クロロフィル-a誘導体もロッド状SAと複合体を形成することが新たにわかり、様々な色素分子を用いて固体状態でのエネルギー移動系を構築することに成功した。 4.光機能性超分子ナノデバイスの評価：ロッド状SAおよびその複合体のデバイス評価を行った。光電流測定により、ロッド状SAが外部へ光電子移動する媒体として有用であることが明らかとなった。また、亜鉛クロロフィルにエネルギーアクセプターを共有結合で連結した分子をロッド状SAと複合化させ、外部へのエネルギー移動系を新たに構築することに成功した。, kaken

  対象リソースIRI
• Apr. 2022, Mar. 2023, Principal investigator, ポリフィリンとキラルYb(III)錯体の連結による近赤外円偏光発光材料の開発, 令和4年度FCC若手フィージビリティ・スタディ支援事業
• Nov. 2023, Nov. 2024, Principal investigator, 有機色素と希土類錯体のハイブリッド化による光機能性カゴ状超分子の開発, 住友財団, 基礎科学研究助成

Ⅲ．社会連携活動実績

１．公的団体の委員等（審議会、国家試験委員、他大学評価委員，科研費審査委員等）

• 複合系の光機能研究会, 将来構想委員会, Apr. 2024, Society